نتایج جستجو برای: N-methylimidazole

تعداد نتایج: 976711  

Journal: :Biological and Pharmaceutical Bulletin 2004

2012
J. MUEHLINGHAUS G. ZUNDEL

IR spectroscopic investigations were conducted with poly-L-histidine (PLH) films, hydrous imidazole and pyrazole solutions and anhydrous ./V-methylimidazole with respect to protonation. Continuous absorption arises with increasing protonation and is maximally intensive with PLH, imidazole and 7V-methylimidazole when 50% protonated. The absorption indicates the formation of N H ® # , , N bonds. ...

2017
Alexei Nikolaevich Kiselev Olga Konstantinovna Grigorova Alexei Dmitrievich Averin Sergei Aleksandrovich Syrbu Oskar Iosifovich Koifman Irina Petrovna Beletskaya

The arylation of mono-, di- and tetra-meso-bromophenyl-substituted porphyrins with the heteroarenes containing "acidic" C-H bonds, such as benzoxazole, benzothiazole and N-methylimidazole was studied in the presence of three alternative catalytic systems: Pd(dba)2/DavePhos/Cs2CO3, Pd(PPh3)4/PivOH/K2CO3 and Pd(OAc)2/Cu(OAc)2/PPh3/K2CO3. The first catalytic system was found to be successful in th...

Journal: :The journal of physical chemistry. A 2007
Stephanie M Villano Adam J Gianola Nicole Eyet Takatoshi Ichino Shuji Kato Veronica M Bierbaum W Carl Lineberger

The 351.1 nm photoelectron spectra of the N-methyl-5-pyrazolide anion and the N-methyl-5-imidazolide anion are reported. The photoelectron spectra of both isomers display extended vibrational progressions in the X2A' ground states of the corresponding radicals that are well reproduced by Franck-Condon simulations, based on the results of B3LYP/6-311++G(d,p) calculations. The electron affinities...

2008

Chem. Abstr. Serv. Reg. No.: 60-56-0 Deleted CAS Reg. Nos: 4708-61-6; 85916-84-3 Chem. Abstr. Name: 1,3-Dihydro-1-methyl-2H-imidazole-2-thione IUPAC Systematic Names: 1-Methylimidazole-2-thiol; 1-methyl-4-imidazoline-2thione Synonyms: 2-Mercapto-1-methyl-1H-imidazole; 2-mercapto-1-methylimidazole; mercazolylum; 1-methyl-1,3-dihydroimidazole-2-thione; N-methylimidazolethiol; 1-methyl-2-imidazole...

Ashraf S. Shahvelayati Fatemeh Sameni Khadijeh Yadollahzadeh

The selective nitrosation of β-dicarbonyl compounds with sodium nitrite was carried out under1-methyl-3-carboxymethylimidazolium chloride, prepared from N-methylimidazole andchloroacetic acid, as an acidic ionic liquid. The reaction was found to proceed under relativelymild conditions with excellent conversion and selectivity. The ionic liquid was recycled andreused.

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