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نتایج جستجو برای Oxyfluoride

تعداد نتایج: 57  
Journal: :Acta crystallographica. Section C, Crystal structure communications 2005
Nicholas F Stephens, Philip Lightfoot,

The title compound, bis(ethylenediaminium) mu-oxo-bis[tetrafluorooxoniobium(V)], (C2H10N2)2[Nb2O3F8], is a novel organically templated niobium oxyfluoride. It consists of isolated [Nb2O3F8]4- octahedral dimers charge balanced by ethylenediaminium cations, two of which lie about inversion centres. Two NbO2F4 octahedra are fused through a common O atom to form the dimers. Characteristic short ter...

2007
Z. Pan, S. H. Morgan,

Upconversion luminescence has been studied for Er in a germanate-oxyfluoride and a tellurium-germanate-oxyfluoride transparent glass-ceramic using 800 nm excitation. Significantly increased upconversion luminescence was observed from transparent glass-ceramics compared with that from their corresponding as-prepared glasses. In addition to a strong green emission centered at 545 nm from S3/2 sta...

2012
Yoshihiro Tsujimoto, Kazunari Yamaura, Eiji Takayama-Muromachi,

In this paper, we review recent progress and new challenges in the area of oxyfluoride perovskite, especially layered systems including Ruddlesden-Popper (RP), Dion-Jacobson (DJ) and Aurivillius (AV) type perovskite families. It is difficult to synthesize oxyfluoride perovskite using a conventional solid-state reaction because of the high chemical stability of the simple fluoride starting mater...

2014
Dong Su, Sung-Wook Kim, Kai He, Nathalie Pereira, Glenn G. Amatucci, Jason Graetz, Feng Wang,

Scanning transmission electron microscopy (STEM)-electron energy loss spectroscopy (EELS) has been used for studying local structure of the energy related materials. High resolution (Cs-corrected) STEM is regarded as a promising technique to observe morphological evolution and atomic arrangement inside single particles. Combining with EELS technique, one could probe the local chemical structure...

2016
Kummara Venkata Krishnaiah, Elton Soares de Lima Filho, Yannick Ledemi, Galina Nemova, Younes Messaddeq, Raman Kashyap,

Oxyfluoride glasses doped with 2, 5, 8, 12, 16 and 20 mol% of ytterbium (Yb(3+)) ions have been prepared by the conventional melt-quenching technique. Their optical, thermal and thermo-mechanical properties were characterized. Luminescence intensity at 1020 nm under laser excitation at 920 nm decreases with increasing Yb(3+) concentration, suggesting a decrease in the photoluminescence quantum ...

2012
Hua Yu, Hui Guo, Ming Zhang, Yan Liu, Min Liu, Li-juan Zhao,

It has been an open question whether Nd3+ ions are incorporated into the crystalline phase in oxyfluoride glass ceramics or not. Moreover, relative research has indicated that spectra characters display minor differences between before and after heat treatment in oxyfluoride glass compared to similar Er3+-, Yb3+-, Tm3+-, Eu3+-, etc.-doped materials. Here, we have studied the distribution of Nd3...

2007
Anthony J. Midey, A. A. Viggiano,

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2010
Paul DeBurgomaster, Jon Zubieta,

The title compound, [V(2)F(2)O(4)(C(12)H(8)N(2))(2)], is a centrosymmetric binuclear vanadium(V) species with the metal ions in a distorted octa-hedral environment. The symmetry-equivalent V(V) atoms exhibit coordination geometries defined by cis-terminal fluoride and oxide groups, unsymmetrically bridging oxide groups and the N-atom donors of the phenanthroline ligands. The crystal packing is ...

2015
Shuhua Ren, Ruiyong Chen, Emad Maawad, Oleksandr Dolotko, Alexander A. Guda, Viktor Shapovalov, Di Wang, Horst Hahn, Maximilian Fichtner,

New high-capacity intercalation cathodes of Li2V x Cr1-x O2F with a stable disordered rock salt host framework allow a high operating voltage up to 3.5 V, good rate performance (960 Wh kg-1 at ≈1 C), and cycling stability.

2015
Fangze Chen, Tao Wei, Xufeng Jing, Ying Tian, Junjie Zhang, Shiqing Xu,

Er(3+) doped oxyfluoride tellurite glasses have been prepared. Three Judd-Ofelt parameters Ωt (t=2, 4, 6) and radiative properties are calculated for prepared glasses. Emission characteristics are analyzed and it is found that prepared glasses possess larger calculated predicted spontaneous transition probability (39.97 s(-1)), emission cross section σem (10.18 × 10(-21)cm(2)) and σem × Δλeff (...