The purpose of this work is to study the esterification liquid olefins with acetic acid in presence catalysts and structure properties synthesized saturated esters. 1-Hexene, 2-methyl-1-pentene, 2-ethyl-1-pentene, 3-methyl-1-pentene, 3-methyl-2-pentene were used as for reaction: H2SO4 HCl. influence various factors (the nature catalysts, relative activity temperature a) on rate reaction was stu...

Amylenes are unsaturated hydrocarbons (C5H10), such as 1-pentene, 2-pentene, 2-methyl-but-1-en (3-methyl-1-butene), 2-methyl-but-2-en (isopentene), and 3-methyl-but-1-en. We investigated bacterial mutagenicity of 1-pentene, 2-pentene, and 3-methyl-but-1-en in the Ames test. 2-Pentene was investigated as racemate and as pure diastereomers. We included the methyltransferase deficient Salmonella T...

2. Fluka nitromethane ( ^ 99.7 mole % ) and the following Fluka hydrocarbons: trans-2-pentene ( ~ 9 9 m o l e % ) , cis-2-hexene ( ^ 9 9 . 5 ) , trans-2hexene ( ~ 99), trans-3-hexene 99), trans-2heptene 99), trans-3-heptene 99), 1-octene (99.73), trans-2-octene ( ^ 99), trans-3-octene ( ^ 9 9 ) , trans-4-octene ( ^ 99), 1-nonene ( > 97), trans-2nonene ( ^ 99), trans-3-nonene ( ^ 99), trans-4-no...

1-Pentene, respectively 1-hexene, were reacted with 13 homogeneous metallocene catalysts to give linear oligomerization products, predominantly dimers, with selectivities above 90%. The product distributions of the codimerization reactions of 1-pentene with 1-hexene reflected a binomial behaviour. Therefore, the ratio for dimers is 1:2:1 (C10:C11:C12) while the trimers (pentadecenes up to octad...

The preparation and synthetic uses of a number of bifunctional reagents (5-chloro-2-trimethylstannyl-2-pentene and related substances, (~)-1-bromo-4-methyl-3-trimethylstannyl-2-pentene, and alkyl (z)and (~)-2,3-bis(trimethylstannyl)-2-alkenoates) are described. In this work a number of useful annulation methods were developed and these annulation sequences played key roles in effecting total sy...

A novel dinuclear complex containing the photo-sensitizing Ru unit and a Pd center is effective toward selective catalytic dimerization of alpha-methylstyrene leading to 2,4-diphenyl-4-methyl-1-pentene under visible-light irradiated conditions.

Studies on the feeding deterrent activity of some natural, cyclic terpenes (myrcene, (+)-3-carene, (+)-limonene, (±)-camphene), synthetic alkenes (2-methyl-1-pentene, 2,4,4-trimethyl-1-pentene, 1-methylcyclohexene, 1-tetradecene) and their derivatives α-methylenelactones in choice and no-choice tests against Colorado potato beetle with potato, Solanum tuberosum L. leaf discs as consuming food w...