In this work, an innovative method is described for the preconcentration of phosphate ions using ethylenediamine functionalized mesopor (MCM-41). Functionalized MCM-41 was synthesized and the presence of organic groups in the silica framework was demonstrated by FTIR spectrum. The amount of organic groups immobilized on silica surface was determined by elemental analysis and TGA. The functi...

in this research, nanoporous silica (sba-15) was physically functionalized using2-(2-nitrobenzylideneamino) guanidine compound. this functionalized sba-15 was utilized as a new sorbentfor separation and preconcentration of some lanthanide ions. inductively coupled plasma optical emissionspectrometry (icp-oes) was used as a detection technique. the preconcentration factor of the method is 100and...

N(2-Thiophenyl)-1-(2-hydoxyphenyl)Imine (NTPHPI) was used as a proper complexing agent for the preconcentration by cloud point extraction followed by atomic absorption spectrometric to determine of Ni, Cu and Co ions in real samples. NTPHPI and Triton X-114 were used as hydrophobic ligand and non-ionic surfactant respectively and the pH of 8 was chosen as optimum. Under the optimized experiment...

An efficient and reusable adsorbent, namely 3-mercaptopropionic acid modified tetraethyl orthosilicate (TEOS) grafted MnFe2O4 nanoparticles (MPA-TEOS-MnFe2O4 NPs) was synthesized and used for the extraction and preconcentration of trace amount of Al (III) and Cr (III) ions in water samples. MnFe2O4 NPs were prepared by chemical c...

Ethylene glycol bisthioglycolate modified gold nanoparticles grafted Mn doped Fe3O4 nanoparticles (Au@Mn-Fe3O4 NPs) adsorbent was synthesized and applied for extraction and preconcentration of trace amounts of Ag+ and Pb2+ ions in artificial and natural saliva. The adsorbent was characterized by transmission electron microscopy (...

Abstract A new adsorbent, ethylene glycol bisthioglycolate modified gold nanoparticles grafted Mn doped Fe3O4 nanoparticles (EGBTG-Au@Mn-Fe3O4 NPs) were synthesized through chemical precipitation followed by an oxidative Mn doping process to use for extraction and preconcentration of trace amounts of Hg, and Cu ions in artificial and natural saliva. The prepared adsorbent was characterize...

in this work, a new, simple and fast method for the solid phase extraction-spectrophotometric determination of phosphate using cetyltrimethyl ammonium bromide immobilized on alumina-coated magnetite nanoparticles (ctab@acmnps) has been developed. the determination of phosphate is based on the molybdenum blue method which was monitored at λmax of 810 nm. mnps and acmnps characterized by sem, vsm...

Polystyrene (PS) was extracted from Styrofoam (expanded polystyrene foam) waste, so called white pollutant. The PS was functionalized with N,NBis(2-aminobenzylidene)benzene-1,2diamine (ABA) ligand through an azo spacer. The resin was characterized by FT-IR spectroscopy and elemental analysis. The PSN=N-ABA resin was used for the enrichment and speciation of Cr(III)/Cr(VI) ions and total Cr dete...

The anodic stripping voltammetric determination of gold was accomplished on a chemically modified glassy carbon electrode in a solution containing chloride ions. A modifying polymer, polyvinylferrocene, was coated by immersing the glassy carbon surface in its solution in methylene chloride followed by solvent evaporation. Tetrahalo complexes of gold, tetrachloroaurate(III) and tetrabromoaurate(...

A novel, simple, sensitive and effective method has been developed for preconcentration of the trace Pb (II) ions in aqueous Samples by CNT carboxyl which in order to improve the performance of extraction and preconcentration was used. Amounting of the ions density in solution was performed by the method of flame atomic absorption spectrometry. The effective parameters on extraction such as: ef...