Watt’s bath and pulse reverse (PR) electrodeposition is used to produce spherical nickelmultiwall carbon nanotubes (Ni-MWCNT) of 2.00, 0.93, 1.63 and 6.71 μm diameter and a variety ofsize distributions. For 60 cycles, an absolute electrodeposition current of 18 A/dm2 is applied atcurrent ratios of ii = idissolution/ideposition = 0, 0.077, 0.200 and 0.368. A simple exponential equation isfitted ...

A review on pulse and pulse reverse techniques for electrodeposition have been attempted. Pulse electrodeposition (PED) of some metals and lloys are reported. The effects of mass, transport, electrical double layer pulse parameters and current distribution on surface roughness and orphology are presented. Applications, advantages and disadvantages of PC and PRC techniques are discussed along wi...

Anodic aluminium oxide (AAO) templates for multi-walled carbon nanotube (MWCNT) growth were produced by anodization of aluminium followed by pulse-reverse electrodeposition of cobalt inside the AAO pores. Cobalt functioned as the catalyst for H2/C2H2 chemical vapour deposition (CVD) growth of fairly well graphitized MWCNTs initiating inside the majority of the AAO pores and quickly growing beyo...

This work focuses on the significance of particle's residence time in composite electrodeposition. Ni-SiC were produced using different pulse-reverse (PR) waveforms based average particle diameter (60 nm). The waveform was designed to deposit a metal thickness equivalent during cathodic pulse and strip half anodic pulse. shape modified study its effect codeposition by changing current density p...

gd2o3 nanoparticles were prepared by a two–step process; cathodic electrodeposition followed by heat-treatment method. first, gd(oh)3 nanoparticles was galvanostatically deposited from nitrate bath on the steel substrate by pulse current (pc) mode. the deposition experiments was conducted at a typical on-time and off-time (ton=1ms and toff=1ms) for 60 min. the electrodeposited precursor was the...

Hydrogen evolution assisted electrodeposition is a new bottom-up technique allowing the fast and simple synthesis of nanometals. Electrochemical dealloying is a top-down approach with the same purpose. In this work, we show that a combination of these two methods in sequence by pulse-reverse electrodeposition can be used to prepare high-surface-area nanostructured metals. Highly porous adherent...

In this study, using 45# carbon steel as the substrate, a first experimental analysis was carried out on polarisation behaviour of different component wattage plating solutions in order to determine reasonable content nanodiamond particles nickel/nanodiamond composite solution. Secondly, effect double-pulse forward and reverse duty cycle working time performance then investigated by testing thi...