in this work, so3h-functionalizedphthalimide (sfp) as a so3h-containing solid acid is prepared by the reaction of phthalimide with chlorosulfonic acid, and characterized by ft-ir, 1h and 13c nmr, mass, tg, dtg, xrd and sem. then, it is utilized as a highly efficient, heterogeneous and green catalyst for the one-pot multi-component condensation of dimedone with arylaldehydes, β-ketoesters and am...

In this study, a solid acid was prepared by the sulfonation of surface modified α-zirconium phosphate (ZrP) single-layer nanosheets (SO3H@ZrP), and the prepared solid acid was investigated for the esterification of oleic acid with methanol to produce biodiesel. For comparison, liquid H2SO4 and commercial Amberlyst® 15 catalyst were also evaluated for the same reaction under the same conditions....

Knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) and resulted in the formation of arylidene and bis-arylidene barbiturates. Excellent yields and short reaction times are related to the high efficiency of SBA-Pr-SO3H that the reactions take place easily in its nano-pores. SBA-Pr-SO3H as ...

knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (sba-pr-so3h) and resulted in the formation of arylidene and bis-arylidene barbiturates. excellent yields and short reaction times are related to the high efficiency of sba-pr-so3h that the reactions take place easily in its nano-pores. sba-pr-so3h as ...

Microporous carbon catalysts with large surface areas (800-1100 m(2) g(-1)) and high densities of SO3H groups (ca. 1.1 mmol g(-1)) were synthesized by sulfonation of zeolite-templated microporous carbon. The resulting SO3H-bearing microporous carbon catalysts exhibited higher catalytic performance for the hydrolysis of cellobiose and the Beckmann rearrangement than conventional solid acid catal...

3,4-ِdihydropyrano[c]chromene derivatives were synthesized using sulfonic acid functionalized silica (sio2-pr-so3h) as a highly efficient heterogenous solid acid catalyst via one-pot three-component condensation of aromatic aldehydes with malononitrile and 4-hydroxycoumarin in excellent yields.

sulfonic acid functionalized sba-15 (sba-pr-so3h) as a new nanoporous acid catalyst was used in the one-pot synthesis of polyhydroquinolines derivatives via the hantzsch four component condensation reaction of aldehydes, b-ketoesters, dimedone and ammonium acetate under solvent free conditions with short reaction time in excellent yields. sba-pr-so3h was proved to be an efficient heterogeneous ...

Knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) and resulted in the formation of arylidene and bis-arylidene barbiturates. Excellent yields and short reaction times are related to the high efficiency of SBA-Pr-SO3H that the reactions take place easily in its nano-pores. SBA-Pr-SO3H as ...

In this article, simple, convenient synthesis of 2-aryl-1- arylmethyl-1H-1,3-benzimidazole (1,2-disubstituted benzimidazoles) via condensation of 1,2-phenylenediamine and aromatic aldehydes using SBA-Pr-SO3H as a nanoporous solid acid catalyst in green protocol was reported.

Based on starch and series of alkyl benzene sulfonic acid as the materials, a novel carbon-based solid acid catalyst is synthesized using hydrothermal method. This catalyst exhibits much higher catalytic activity in the reaction of esterification of Mono-fatty alcohol polyoxyethylene maleate esters with 1,4-butanediol. The structure of carbon-based solid acid catalyst was charactered by IR and ...