A continuous flow sonochemical reactor was developed capable of producing metastable cadmium sulfide (CdS) nanoplatelets with thicknesses at or below 10nm. The continuous flow sonochemical reactor included the passive in-line micromixing of reagents prior to sonochemical reaction. Synthesis results were compared with those from reactors involving batch conventional heating and batch ultrasound-...

Little is known about the efficacy of pulsed ultrasound compared with continuous ultrasound. Previous studies on the efficacy of pulsed ultrasound were not systematic and gave different results. In this study, the effects of pulse length, pulse interval, pulse length × pulse intervals, and treatment time on sonochemical activity were investigated using a simple oxidation of iodide method and a ...

Ultrasonic irradiation has been shown to effectively degrade perfluorinated chemicals (PFCs) such as perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in aqueous solution. Reduced PFC sonochemical degradation rates in organic-rich groundwater taken from beneath a landfill, however, testify to the negative kinetic effects of the organic groundwater constituents. In this study, the P...

The effect of sonochemical reactors (SCR) technology upon the degradation of reactive yellow dye has been studied and reported here. Sonochemical reactors (ultrasound irradiation) produce strong cavitation in aqueous solution causing shock wave and reactive free radicals by the violent collapse of the cavitation bubble. These effects should contribute to destruction as well as the decomposition...

We present an efficient sonochemical microreactor system based on micromachined surfaces which generate microbubbles in a liquid when exposed to an ultrasonic field. Cavitation of these bubbles leads to radical formation, introducing chemical reactions in the solution. The system exhibits a high sonochemical yield at conditions which would otherwise not produce any significant chemical effect, ...

As one of several types of pollutants in water, chlorinated compounds have been routinely subjected to sonochemical analysis to check the environmental applications of this technology. In this review, an extensive study of the influence of the initial concentration, ultrasonic intensity and frequency on the kinetics, degradation efficiency and mechanism has been analyzed. The sonochemical degra...

The sonochemical decomposition of volatile organometallic compounds produces high surface area solids that consist of agglomerates of nanometer clusters. For iron pentacarbonyl and tricarbonylnitrosylcobalt, nanostructured metals and alloys are formed; for molybdenum hexacarbonyl, the metal carbide is produced. These sonochemically produced nanostructured solids are active heterogeneous catalys...

Fundamental knowledge on intrinsic plutonium colloids is important for the prediction of plutonium behaviour in the geosphere and in engineered systems. The first synthetic route to obtain salt-free intrinsic plutonium colloids by ultrasonic treatment of PuO2 suspensions in pure water is reported. Kinetics showed that both chemical and mechanical effects of ultrasound contribute to the mechanis...

Perfluorinated chemicals such as perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) are environmentally persistent and recalcitrant to most conventional chemical and microbial treatment technologies. In this paper, we show that sonolysis is able to decompose PFOS and PFOA present in groundwater beneath a landfill. However, the pseudo first-order rate constant for the sonochemica...

A new sonochemical process for the top-down production of silicon nanoparticles (<1 nm) with surface functional groups is described. The procedure involves a combination of acoustic cavitation erosion of a single-crystalline silicon surface coupled with simultaneous reaction with a reactive organic compound such as 1-hexyne. The sonochemical formation of the photoluminescent silicon nanoparticl...