نتایج جستجو برای: Soot Oxidation

تعداد نتایج: 120227  

Journal: :iranian journal of chemistry and chemical engineering (ijcce) 2007
kazem bashirnezhad mohammad moghiman iman zahmatkesh

the present study is concerned with measuring and simulating soot formation and combustion in turbulent liquid fuel spray flames. soot concentrations inside the combustor are measured by filter paper technique. the simulation is based on the solution of the fully-coupled conservation equations for turbulent flow, chemical species kinetic modeling, fuel droplet evaporation and combustion and soo...

Iman Zahmatkesh Kazem Bashirnezhad Mohammad Moghiman,

The present study is concerned with measuring and simulating soot formation and combustion in turbulent liquid fuel spray flames. Soot concentrations inside the combustor are measured by filter paper technique. The simulation is based on the solution of the fully-coupled conservation equations for turbulent flow, chemical species kinetic modeling, fuel droplet evaporation and combustion and...

2006
C. H. Kim F. Xu P. B. Sunderland G. M. Faeth

The flame and soot structure, including soot primary particle nucleation, surface growth and oxidation properties, of 6 premixed and 20 diffusion flames were studied experimentally for various fuels, at temperatures of 1400-2350 K and at pressures of 13-811 kPa (0.1-8.0 atm). Measurements were made along the axes of flames with the reactants at normal temperature (300 K). The following properti...

2008
Jian Liu Zhen Zhao Peng Liang Chunming Xu Aijun Duan Guiyuan Jiang Wenyong Lin Israel E. Wachs

The reaction mechanisms for diesel soot oxidation over V4/ZrO2 or V4/TiO2 oxide catalysts were studied by the means of in-situ UV-Raman spectroscopy. The results indicate that the formation of surface oxygen complexes (SOC) is a key step and the SOC species mainly exist as carboxyl groups. The presence of NO in the reaction gas stream can promote the formation of SOC species. For soot oxidation...

Journal: :Journal of environmental sciences 2013
Ali Alinezhadchamazketi Abas Ali Khodadadi Yadollah Mortazavi Ahmad Nemati

Series of mixed metal oxides were synthesized by gel-combustion method and their catalytic activities for soot oxidation were investigated. The catalysts were M-Ce-Zr (M = Mn, Cu, Fe, K, Ba, Sr), and xK-20Mn-Ce-Zr (x = 0, 5, 10, 20), they were characterized by XRD, SEM, TPR and BET surface area techniques. The results of soot temperature programmed oxidation (TPO) in an O2 oxidizing atmosphere ...

Journal: :Environmental science & technology 2005
S H Kim R A Fletcher M R Zachariah

The purpose of this paper is to address the differences observed in the oxidative kinetics between flame and diesel derived soots. In particular, it has been observed that flame soot has a significantly higher activation energy for oxidation than does diesel soot. The hypothesis tested in this paper is that metals, possibly coming from lubricating oils, within diesel generated soot particles ma...

2009
Yongfeng Liu Youtong Zhang Hongsen Tian Lianda Liu

To calculate soot source terms a new detailed kinetic soot model is applied to study the formation and oxidation of soot particles in turbulent flames. The model is based on a detailed description of the chemical and physical processes leading to the formation of soot. It can be subdivided into the growth of polycyclic aromatic hydrocarbons (PAHs) in the gas phase reactions and the processes of...

Journal: :Nanoscale 2016
Chunmei Cao Xingang Li Yuqing Zha Jing Zhang Tiandou Hu Ming Meng

Crossed Fe2O3 nanosheets supported cobalt oxide nanoparticles on three-dimensionally macroporous nickel foam substrate (xCo/Fe-NF) was designed and successfully prepared through a facile hydrothermal and impregnation route. These catalysts showed high catalytic soot combustion activities under self-capture contact mode. The three-dimensional macroporous structures of Ni foam and the crossed Fe2...

2012
Maria-Eugenia Becerra Maria-Jose Illán-Gómez Agustin Bueno-López

Alumina-supported manganese catalysts with cryptomelane and/or birnessite structure have been prepared using a simple method based on the thermal decomposition of potassium permanganate. The samples have been characterized by XRD, FTIR, TGA, DSC, N2 adsorption at −196 °C, SEM, H2-TPR and XPS, and their catalytic activity for soot combustion has been tested and compared to that of a reference Pt...

2012
Sujith Sukumaran Cuong Van Huynh Song-Charng Kong Nam Hyo Cho

Introduction The present day oil crisis and need for more fuel economy has driven the demand for diesel powered automobiles. Diesel soot is one of the primary emissions of diesel combustion and accurate modeling of soot formation is a challenging area for combustion researchers. The soot formation in diesel engine combustion has been previously modeled using a twostep phenomenological model whi...

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