In order to study the sulfidation of a catalyst fixed bed, an in operando single pellet sensor was designed. A catalyst pellet from the fixed bed was electrically contacted and its electrical response was correlated with the catalyst behavior. For the sulfidation tests, a nickel catalyst was used and was sulfidized with H₂S. This catalyst had a very low conductivity in the reduced state. During...

The present work is concerned with sulfidation of Cu, Zn and Ni containing plating wastewater with CaS. The sulfidation experiments were carried out at a room temperature by adding solid CaS to simulated metal solution containing either single-metal of Ni, Zn and Cu, or Ni-Zn-Cu mixture. At first, the experiments were conducted without pH adjustment and it was found that the complete sulfidatio...

Two-dimensional and layered MoS2 is a promising candidate for next-generation electric devices due to its unique electronic, optical, and chemical properties. Chemical vapor deposition (CVD) is the most effective way to synthesize MoS2 monolayer on a target substrate. During CVD synthesis, sulfidation of MoO3 surface is a critical reaction step, which converts MoO3 to MoS2. However, initial rea...

The selective recovery of heavy metals of Cu, Zn, Ni and Cr from a mixed plating sludge by sulfidation and oxidation treatment was targeted in this study. At first, the mixed plating sludge was simultaneously subjected to an extraction and Cu sulfidation process at pH=1.5 to dissolve heavy metals and to precipitate Cu as CuS. In the next step, the sulfidation treatment of Zn was carried out at ...

Sulfidation of metallic nanoparticles such as silver nanoparticles (AgNPs) released to the environment may be an important detoxification mechanism. Two types of AgNPs-an engineered polydisperse and aggregated AgNP powder, and a laboratory-synthesized, relatively monodisperse AgNP aqueous dispersion-were studied. The particles were sulfidized to varying degrees and characterized to determine th...

The mechanism of ZnO sulfidation with sulfur and iron oxide at high temperatures was studied. The thermodynamic analysis, sulfidation behavior of zinc, phase transformations, morphology changes, and surface properties were investigated by HSC 5.0 combined with FactSage 7.0, ICP, XRD, optical microscopy coupled with SEM-EDS, and XPS. The results indicate that increasing temperature and adding ir...

A facile synthesis of Ag2S-hollow Fe2O3 nanocomposites with NIR photoluminescence was firstly demonstrated by the sulfidation of Ag-Fe2O3 core-shell nanoparticles. Characteristic morphology transformations along with color changes were recorded and a mechanism was proposed for the sulfidation process, which can provide new possibilities to fabricate other complex nanostructures.

Fe2O3/ZSM-5 modified with Ce via citrate route (sol-gel approach) is applied for H2S removal in 500–700 ◦C temperature range. The sulfidation activity of Fe2O3/ZSM-5 is appreciably promoted by introduction of Ce plausibly attributed to the synergy of Fe2O3 and CeO2. 5Fe5Ce/ZSM-5 performs the optimal desulfurization behavior at 600 ◦C with sulfur capacity of 1020 μmol S/g, and the sulfidation pr...

Nanomaterials are highly dynamic in biological and environmental media. A critical need for advancing environmental health and safety research for nanomaterials is to identify physical and chemical transformations that affect the nanomaterial properties and their toxicity. Silver nanoparticles, one of the most toxic and well-studied nanomaterials, readily react with sulfide to form Ag(0)/Ag2S c...

Binary Cu-Cr-O and Cu-Ce-O oxides were studied in this work as regenerable sorbents for high-temperature fuel gas desulfurization. CuO-Cr2O3 and CuO-CeO2 sorbents can remove H2S from simulated coal-derived fuel gas to less than 5-10 ppmv in the temperature range of 650-850 °C. The presence of stable CuCr2O4 in CuO-Cr2O3 solids retains some copper in the Cu2+ or Cu1+ oxidation state, which can a...