the muscle-like technology would be of enormous advantages for biomedical applications such as medical implants and human assist devices. ionic polymer metal composites (ipmcs) are one kind of biomimetic actuators. an ionic polymer metal composite composed from an ionomer with high ion exchange capacity that packed between two thin metal layers. in the present study we focused on the preparatio...

The ability to chemically wire ionomer films to electrode surfaces can promote transport near interfaces and impact a host of energy-related applications. Here, we demonstrate proof-of-concept principles for the surface-initiated ring-opening metathesis polymerization (SI-ROMP) of norbornene (NB), 5-butylnorbornene (NBH4), and 5-perfluorobutylnorbornene (NBF4) from Pt-modified gold substrates a...

New bionanocomposite proton exchange membranes were prepared from sulfonated polybenzimidazole (s-PBI) and various amounts of sulfonated ZnO/cellulose nanohybrids (ZnO/cellulose-SO3H). The use of ZnO/cellulose-SO3H compensates for the decrease in ion exchange capacity of membranes observed when non-sulfonated nano-fillers are utilized. The strong –SO3H/–SO<su...

      The muscle-like technology would be of enormous advantages for biomedical applications such as medical implants and human assist devices. Ionic polymer metal composites (IPMCs) are one kind of biomimetic actuators. An ionic polymer metal composite composed from an ionomer with high ion exchange capacity that packed between two thin metal layers. In the present study we focused on the prep...

The photostability of various electro-optic active guest–host polymers, doped with chromophores that possess very efficient cyano-containing acceptors and dialkyaminoor diarylamino-benzenes, and also their extended thiophene analogs as bridging structures, has been investigated over a broad wavelength range in the near infrared and the visible. A variation of over 2 orders of magnitude was foun...

We have investigated two polymeric materials for incorporating high-Z metallic elements into ablation layers. Although each method ut~lizes solution-coating techniques, the materials and the resulting structures are basically different. The first, sulfonated polystyrene, which has a metal content of up to 5 atomic percent, is easily prepared and can easily be coated from solution. The second ma...

Various polybenzimidazole (PBI)-based ion-exchange films were prepared and thoroughly characterized by Fourier transform infrared (FT-IR) spectroscopy, proton conductivity, and water uptake for possible use as fuel cell membranes. Upon the increase in the flexibility of the PBI-based polymer films (e.g., poly(oxyphenylene benzimidazole) (OPBI) and sulfonated OPBI (s-OPBI)), the membranes exhibi...

sulfonated poly (ether ether ketone) (speek) with a low degree of sulfonation (ds = 40%) was prepared for proton exchange membrane fuel cells (pemfc). poly (ether ether ketone) (peek) was sulfonated in concentrated h2so4 under n2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (h-nmr) technique. after preparation of the speek polymer, the obtained polymer was dissolved i...

The sulfonated polyphenylene ionomer, SPP-QP, being used as the anode binder, improves durability of polymer electrolyte fuel cells in gas exchange cycle test simulating start-up conditions.

Investigations of protein-polyelectrolyte complexes are important in the design of many biomedical applications that include enzyme immobilization, drug delivery, biosensor design, and in bioprocessing where complexation with polyelectrolytes is used to prevent protein aggregation and for protein purification. In this work, we choose to study the effect of polyelectrolyte stereochemistry on the...