one series of half-analogues of michler’s ketone containing one or more terminal methoxysubstituents with variable tertiary amino groups have been used in this study. nmr spectralresults for the parent ketones confirm earlier findings that ortho proton shifts are apparentlyindependent from steric effects in derivatives of michler’s ketone because the ring current andcarbonyl-induced shifts are ...

One series of half-analogues of Michler’s ketone containing one or more terminal methoxysubstituents with variable tertiary amino groups have been used in this study. NMR spectralresults for the parent ketones confirm earlier findings that ortho proton shifts are apparentlyindependent from steric effects in derivatives of Michler’s ketone because the ring current andcarbonyl-induced shifts are ...

In this research, several series of triarylmethane dyes containing one or more terminal methoxy substituents with a variable tertiary amino groups have been used. These dyes have been applied to different substrates by using various methods including transfer printing and then their fastness properties were measured. These dyes shows exceptionally high light fastness (6-7) on acid modified poly...

The structure formation in acid promoted polycondensation and particularly in alkaline post-treatment with urea was studied by 13C NMR spectroscopy in the three-step synthesis of ureaformaldehyde resins. Trishydroxymethyl urea was identified as the constituent of the mixture of hydroxylmethylated urea derivatives obtained in alkaline conditions. The formation of methylenes linked to secondary o...

Control of the spacing between a dimethylamino group and polarised alkene by remote constraints determines if groups make n–π* interaction, form Me2N–C bond or (MeN)CH2–C initiated tertiary amino effect.

The ThYme (Thioester-active enzYme; http://www.enzyme.cbirc.iastate.edu) database has been constructed to bring together amino acid sequences and 3D (tertiary) structures of all the enzymes constituting the fatty acid synthesis and polyketide synthesis cycles. These enzymes are active on thioester-containing substrates, specifically those that are parts of the acyl-CoA synthase, acyl-CoA carbox...

The present work comprises the synthesis of one series of diarylmethane dyes containing one or more terminal methoxy substituents together with a variable tertiary amino group. The electronic absorption spectra of the dyes have been determined. As the conjugation of the terminal nitrogen atom improves in the sequence NMez > Kairoline > Julolidine, a progressive hypsochromic shift is observed

1. The reaction of exo-ci8-3,6-endoxo-A4-tetrahydrophthalic anhydride with amino groups ofmodel compounds and lysozyme is described. 2. Reaction with the e-amino group of Na-acetyl-L-lysine amide gives rise to two diastereoisomeric products; at acidpH the free amino group is liberated with anchimeric assistance by the neighbouring protonated carboxyl group with a half-time of 4-5h at pH 3.0 and...