in order to fabrication of transparent glass-ceramics with li-mica nano crystals, the glasses with chemical composition of 94.9 mass% li(1+x)mg3alsi3(1+x)f2 (x=0.5) with 5.1 mass% mgf2 were crystallized. the glasses were fabricated via the conventional melt-quenching technique. mica crystals were precipitated in the glass phase by later heat treatment. glass samples had glass transition tempera...

Rare earth doped glass-ceramics transparent in the infrared region up to 16 μm have been prepared and studied. The enhancement of the emission of Er 3+ ions at 1.54 μm with increasing crystallinity was demonstrated in a seleniumbased glass-ceramic having a composition of 80GeSe2-20Ga2Se3+1000 ppm Er. The optical transmission, microstructure and luminescence properties of a base glass and glass-...

In order to fabrication of transparent glass-ceramics with Li-mica nano crystals, the glasses with chemical composition of 94.9 mass% Li(1+x)Mg3AlSi3(1+x)F2 (x=0.5) with 5.1 mass% MgF2 were crystallized. The glasses were fabricated via the conventional melt-quenching technique. Mica crystals were precipitated in the glass phase by later heat treatment. Glass samples had glass transition tempera...

The nanoscale microstructure and chemistry of a transparent gahnite glass-ceramic its precursor glass were investigated using atom probe tomography, transmission electron microscopy, nuclear magnetic resonance spectroscopy. In the annealed glass, statistically significant ZrO clustering was observed along with Si depletion within 2 nm clusters. This is expected to be first step in nucleation cr...

transparent glasses in a system of li2o-mgo-sio2-al2o3-fchemical constituents were prepared by melt quenching method. in the fabrication of nanocrystal glass-ceramics, controlled nucleation and subsequent crystal growth were necessary to avoid loss of transparency. it was therefore important to understand thermal properties and crystallization kinetics of the glass ceramics. the crystallization...

Fluoride glasses are of great interest for optical applications, as low phonon energy hosts for rare-earth ions. With an increasing need for more compact optical devices that impose higher dopant concentration, research activity has been focused on the fabrication of fluoride glass planar waveguides to produce integrated lasers and optical amplifiers, especially those based on Er3þ-doped glasse...

Technology of active glass-ceramics (GC) is an important part of luminescent materials engineering. The classic method to obtain GC is based on annealing of parent glass in proper temperature and different time periods. Generally, only the bulk materials are investigated as a starting host for further applications. However, the effect of an additional heat-treatment process on emission and stru...

Tm3+/Yb3+ codoped transparent glass ceramic containing β-PbF2 nanocrystals was successfully prepared. After thermal treatment, emissions from the state of Tm3+ excited by 980 nm laser were greatly quenched by cross relaxation and the 700 nm luminescence from Tm3+:3F2,3→3H6 transition was strongly enhanced. A nearly monochromatic red luminescence band was observed. Based on the luminescence deca...

Upconversion luminescence has been studied for Er in a germanate-oxyfluoride and a tellurium-germanate-oxyfluoride transparent glass-ceramic using 800 nm excitation. Significantly increased upconversion luminescence was observed from transparent glass-ceramics compared with that from their corresponding as-prepared glasses. In addition to a strong green emission centered at 545 nm from S3/2 sta...

 Oxyfluoride glass ceramics containing CaF2nano-crystals doped with Y3+ ions were prepared by one-step crystallization of SiO2- Al2O3- CaO- CaF2 glasses at different temperatures. X- ray diffraction (XRD) results have revealed that CaF2 was the only precipitated crystalline phase in glass ceramic samples. According to the XRD results, a glass ceramic was selected as the best sample in order to ...