the ultra-nanocrystalline diamond (uncd) was synthesized by the detonation of a high explosive mixture in water confinement. the presence of a diamond phase was revealed by x-ray diffraction (xrd) and transmission electron microscopy (tem). x-ray line broadening (xrlb) was used to evaluate the peak profiles of diamond nanoparticles and their corresponding average crystallite sizes. the micro st...

The Ultra-nanocrystalline diamond (UNCD) was synthesized by the detonation of a high explosive mixture in water confinement. The presence of a diamond phase was revealed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). X-ray line broadening (XRLB) was used to evaluate the peak profiles of diamond nanoparticles and their corresponding average crystallite sizes. The micro st...

Colloidal dispersion is essential for most nanodiamond applications, but its influence on nanodiamond electronic properties remains unknown. Here we have probed the electronic structure of oxidized detonation nanodiamonds dispersed in water by using soft X-ray absorption and emission spectroscopies at the carbon and oxygen K edges. Upon dispersion in water, the π* transitions from sp(2)-hybridi...

Nanodiamonds are of interest as nontoxic substrates for targeted drug delivery and as highly biostable fluorescent markers for cellular tracking. Beyond optical techniques, however, options for noninvasive imaging of nanodiamonds in vivo are severely limited. Here, we demonstrate that the Overhauser effect, a proton-electron polarization transfer technique, can enable high-contrast magnetic res...

Nanodiamond in a 2-5-nm size interval (which is typical for an appearance of quantum confinement effect) show Raman spectra composed of 3 bands at 1325, 1600, and 1500 cm-1 (at the 458-nm laser excitation) which shifts to 1630 cm-1 at the 257-nm laser excitation. Contrary to sp2-bonded carbon, relative intensities of the bands do not depend on the 458- and 257-nm excitation wavelengths, and a h...

Since invention of the diamond anvil cell technique in the late 1950s for studying materials at extreme conditions, the maximum static pressure generated so far at room temperature was reported to be about 400 GPa. Here we show that use of micro-semi-balls made of nanodiamond as second-stage anvils in conventional diamond anvil cells drastically extends the achievable pressure range in static c...

The catalytic activity of detonation nanodiamond and its modifications obtained through treatment with hydrogen or air at elevated temperatures is studied in the conversion of C2–C3 alcohols. The catalysts were characterized by means of electron microscopy, optical (FTIR) spectroscopy, elemental analysis and pulse microcatalytic method. It has been established that nanodiamond exhibits high cat...

A nanodiamond with a mean particle size of 4 nm, which was prepared by the detonation of a nanodiamond, has been characterized and used as a collector for tungstate in water samples. An aqueous solution of nanodiamond was found to be stable over the pH range from 3 to 10. Coagulation of the nanodiamond could be brought about by adding an electrolyte solution. The adsorption characteristics of n...