Malachite green (MG) is currently posing a carcinogenic threat to the safety of human lives; therefore, it is highly desirable to develop an effective method for fast trace detection of MG. Herein, for the first time, this paper presents a systematic study on polymer microspheres, being prepared by combined Pickering emulsion polymerization and molecular imprinting, to detect and purify MG. The...

Caffeic acid (CA) is well known for its strong adsorption on metal or metal oxide surfaces mostly due to the catecholic functional group. On the other hand, the detailed adsorption configurations and the effects of functional groups on molecular adsorption have not been clarified yet. In this study, first-principles calculations were implemented to elucidate the adsorption phenomena of CA and i...

abstract phosphate is an essential element for plants, animals, and human. mobility and availability of phosphate in the natural systems is controlled by the adsorption-desorption and dissolution-precipitation reactions. iron (hydr)oxides including goethite play an important role in phosphate adsorption reactions in soil. surface area, crystallinity, and morphology of iron (hydr)oxides are the ...

in this study, a series of laboratory tests were conducted to investigate the efficiency of hydroxyapatite (1-iap)nanopowders towards adsorption of lysozyme from aqueous solution. in the present research. i rp nanopowderssynthesized from egg-shell characterized using sem and ft-ht. the adsorption of lysozyme was i mg/ml using0.1 g adsorbent in 100 ml of lysozyme solution. adsorption data were f...

We discuss the thermodynamics of physical adsorption of gases in porous solids. The measurement of the amount of gas adsorbed in a solid requires specialized volumetric and gravimetric techniques based upon the concept of the surface excess. Excess adsorption isotherms provide thermodynamic information about the gas-solid system but are difficult to interpret at high pressure because of peculia...

Adsorption of malachite green (MG) from aqueous solution onto treated ginger waste (TGW) was investigated by batch and column methods. The effect of various factors such as initial dye concentration, contact time, pH and temperature were studied. The maximum adsorption of MG was observed at pH 9. Langmuir and Freundlich isotherms were employed to describe the MG adsorption equilibrium. The mono...

Single and ternary solute gas phase adsorption isotherms were conducted in this study to evaluate the effectiveness of a simple constant volume method, which was utilized by using Tedlar gas sampling bags as a constant volume batch reactor. For this purpose, gas phase adsorption of toluene, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK) on two types of activated carbons, BPL-bitum...

Methane gas, as one of the major biogases, is a potential source of renewable energy for power production. Biochar can be readily used to purify biogas contaminants such as H2S and CO2. This study assessed the adsorption of CH4, H2S, and CO2 onto four different types of biochars. The adsorption dynamics of biochars were investigated in a fixed-bed column, by determining the breakthrough curves ...

Exfoliated graphite nanoplatelets (xGnP), which combine the layered structure and low price of nanoclays with the superior mechanical, electrical, and thermal properties of carbon nanotubes, are very cost-effective, and can simultaneously provide a multitude of physical and chemical property enhancements. In this study, we evaluated xGnP's adsorption performance of volatile organic compounds (V...

Adsorption of metal cations onto a cellular membrane changes its properties, such as interactions with charged moieties or the propensity for membrane fusion. It is, however, unclear whether cells can regulate ion adsorption and the related functions via locally adjusting their membrane composition. We employed fluorescence techniques and computer simulations to determine how the presence of ch...