Fourier transform infrared absorption spectroscopy has been used to study the adsorption of methanol on the clean Ru(0001) surface at T<or=80 K. Thereby, clear evidence for intact adsorption has been found. This observation contradicts previous studies which suggested an OH (OD) bond scission upon adsorption of methanol on Ru(0001), even at low temperatures, as well as partial recombinative des...

Valonia tannin (VT) was gelated through polymerization with formaldehyde to prepare an adsorbent, which was found effective to remove Ag from aqueous solution. The adsorption–desorption behaviors of valonia tannin resin (VTR) were investigated under various initial Ag concentrations, solution temperatures, pH values etc. The applicability of empirical kinetic models was also studied. The pseudo...

Adsorption and desorption behavior of Bovine Serum Albumin (BSA) on surface-modified magnetic nanoparticles covered with thermosensitive polymer (PNIPAM) was investigated as a function of temperature, pH, and ionic strength. Functionalization of surface-modified magnetic particles was performed by seed polymerization using N-isopropylacrylamide (PNIPAM) as the main monomer. Characterization of ...

The kinetics and mechanisms of molybdate adsorption/desorption at the g-Al2O3/water interface were studied by using the pressure-jump apparatus with conductivity detection at 298 K. A double relaxation was observed due to the adsorption/desorption process. Adsorption data and triple-layer model (TLM) simulation results suggest the formation of both monoand bidentate innersphere complexes (SMoO4...

experiments were conducted to study the ability of surfactant-modified clinoptilolite for molybdate adsorption from aqueous solutions. clinoptilolite was treated with some cationic surfactants. adsorption of surfactants on zeolite surface was confirmed by chemical analysis, ir (infra-red spectroscopy), dtg (derivative thermogravimetry) and sem (scanning electron microscopy) techniques. the modi...

one of the cooling systems that has received considerable attentions in recent years is the adsorption chiller, which works based on the adsorption and desorption of a working fluid in a solid porous bed. different parameters such as fin height directly affect the bed heat and mass transfer processes, and therefore, the performance of the adsorption chillers. in the present study a numerical mo...

The present work investigates the efficiency of the nickel oxide/carbon nanotube (NiO/CNT) nanocomposite for the removal of Cd2+ metal ions from an aqueous. The NiO/CNT nanocomposite was synthesized by the direct co-precipitation method in an aqueous media in the presence of CNTs. The resulting materials were characterized by FT-IR, XRD, SEM, N2 adsorption-desorption</em...

in the present study seven synthetic polymers were used as adsorbents for the removal of cd(ii) from aqueous solution. the equilibrium studies were systematically carried out in a batch process, covering various process parameters that include agitation time, adsorbent dosage, and ph of the aqueous solution. the analyzing system was an atomic absorption spectrometer (perkin-analyst 100). it was...

Self-assembled multilayers were fabricated from lignosulfonate (LS) and poly(diallyldimethylammonium chloride) (PDAC), and the adsorption and desorption behaviors of LS on the LS/PDAC multilayers under different pH conditions were intensively investigated. Results showed that the adsorption and desorption behaviors were controlled by electrostatic attraction, hydrophobic interaction, and change...

the dynamics of multicomponent adsorption in a fixed bed adsorber is examined numerically. the dynamic model of adsorption in the packed column included axial dispersion and variable space velocity along the bed for the multicomponent adsorption adsorption the pore fluid and the solid phase are in equilibrium with a nonlinear isotherm. the numerical solution is based upon the modified lax-wendr...