The electrode reactions of haloargentates were investigated in an aprotic and hydrophobic amide-type ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) the presence halide ions. Silver halides, AgX (X – = Cl , Br I ) found to be soluble BMPTFSA containing 0.5 M BMPX form halogenocomplex, [AgX 3 ] 2– . cathodic reduction metallic Ag was observed within electr...