A novel ligand, 5,5'-(2,2'-bipyridine-4,4'-diyl)-bis(thiophene-2-carboxylic acid) (BTC), and its Ru(II) complex (BTC-1) in which the anchoring group is attached to the thiophene units were developed. Using a low-volatility electrolyte and 3.3 mum mesoporous TiO2 films BTC-1 achieved a solar-to-electricity conversion efficiency of 6.1%, compared to 4.8% for N719 under the same experimental condi...

A novel heteroleptic Ru II complex (BTC-2) employing 5,5 ′ -(2,2 ′ -bipyridine4,4 ′ -diyl)bis (thiophene-2-carboxylic acid) (BTC) as the anchoring group and 4,4 ′ dinonyl-2,2 ′ -bipiridyl and two thiocyanates as ligands is prepared. The photovoltaic performance and device stability achieved with this sensitizer are compared to those of the Z-907 dye, which lacks the thiophene moieties. For thin...

Using linear wave theory, the rate at which energy is converted into internal gravity waves by the interaction of the barotropic tide with topography in an ocean is calculated. Bell’s formula for the conversion rate is extended to the case of an ocean of finite depth H with weak two-dimensional topography h(x, y) and arbitrary buoyancy frequency N(z). Approximate solutions are computed using th...

Low-level barotropic dynamics may help to explain the modulation of eastern and western North Pacific tropical cyclones by the Madden–Julian oscillation (MJO) during Northern Hemisphere summer. The MJO is characterized by alternating periods of westerly and easterly 850-mb zonal wind anomalies across the tropical Pacific Ocean. When MJO 850-mb wind anomalies are westerly, small-scale, slow-movi...

The role of scale interactions in the maintenance of eddy kinetic energy (EKE) during the extreme phases of the intraseasonal oscillation (ISO) is examined through the construction of a new eddy energetics diagnostic tool that separates the effects of ISO and a low-frequency background state (LFBS; with periods longer than 90 days). The LFBS always contributes positively toward the EKE in the b...

The synthesis of highly crystalline macro-meso-microporous monolithic Cu3(btc)2 (HKUST-1; btc(3-) = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)2-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.

previous studies show that the north atlantic oscillation (nao) is the dominant mode of variability in the northern hemisphere winter with marked climatic effects on its downstream regions. in this article the effects of some important forcing terms in the time tendency equation of the eddy kinetic energy (eke) in critical positive months (cpm) and critical negative months (cnm) of the nao are ...

Bacillus subtilis lipase (BSL2) has been successfully immobilized into a Cu-BTC based hierarchically porous metal-organic framework material for the first time. The Cu-BTC hierarchically porous MOF material with large mesopore apertures is prepared conveniently by using a template-free strategy under mild conditions. The immobilized BSL2 presents high enzymatic activity and perfect reusability ...

manganese metal-organic framework (mn-mof) containing mn2+ ions, benzenetricarboxylic acid (btc) and n,n-dimethylformamid (dmf) was prepared and used as catalyst for oxidation of alkenes such as 1,1-diphenylethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene to epoxides with 33-92% conversion and 75-100% selectivity and oxidation of alkanes such as fluorene, adamantane, e...

The energy flux out of barotropic tides and into internal waves (‘‘conversion’’) is computed using a global domain multi-layer numerical model. The solution is highly baroclinic and reveals a global field of internal waves radiating way from generation sites of rough topography. A small number of sites where intense internal wave generation occurs accounts for most of the globally integrated wo...