Understanding the fundamentals of arsenic adsorption and oxidation reactions is critical for predicting its transport dynamics in groundwater systems. We completed batch experiments to study the interactions of arsenic with a common MnO2(s) mineral, pyrolusite. The reaction kinetics and adsorption isotherm developed from the batch experiments were integrated into a scalable reactive transport m...

Adsorption of different oxidation species of selenium (Se), selenate (SeO4) and selenite (SeO3), with varying pHs (2-10) and ionic strengths (I=0.01 M, 0.1 M and 1.0 M NaNO3) was measured on quartz, aluminum oxide, and synthetic iron oxide (ferrihydrite) using batch reactors to obtain a more detailed understanding of the adsorption mechanisms (e.g., innerand outer-sphere complex). In addition t...

in this research, the batch removal of toxic hexavalent chromium ions from wastewater and aqueous solution using dried (bd) sargassum sp. (brown marine algae) and activated carbon (ac) prepared from it was examined. biomass, ph and the initial concentration of cr(vi), adsorption models and kinetic studies were investigated. the experiment was performed in a batch system and theeffect of solutio...

The adsorption study was conducted on three Japanese soils with different soil properties to characterize the adsorption pattern of Arsenic (As). Double tube method was used to find out the effect of soil moisture levels on As adsorption. For this study, besides double tube method, conventional batch method also was used. The As adsorption showed two phase kinetics. An initial and rapid adsorpt...

Insoluble Dendronized Chitosan (DCTS) was prepared to improve the adsorption capacity of chitosan (CTS) as well as to lower its solubility at lower pH for efficient removal of acid dye, Acid Blue 9 (AB 9) from aqueous solutions. Dendronized chitosan was prepared by grafting ‘dendrimer-like’ Polyamidoamine (PAMAM) onto CTS surface using Michael addition reaction followed by amidation reaction. T...

In the present work, different methods were tested to evaluate the adsorption and desorption of metalaxyl in two acid soils with different organic carbon and clay contents. The three methods (batch, stirred flow chamber and column) that were examined produced similar findings when the two soils were compared: (a) the metalaxyl adsorption capacity was higher in the soil with higher organic matte...

Treatment of stormwater via sorption has the potential to remove both colloidal and dissolved pollutants. Previous research shows that activated carbon produced from sewage sludge is very efficient in sorbing hydrophobic organic compounds (HOCs), frequently detected in stormwater. The aim of this research was to determine whether the presence of dissolved organic matter (DOM) has a negative eff...

This paper investigates the bioseparation of binary protein mixtures using polystyrene based anion exchange resin. Adsorption experiments were conducted in batch mode using draft-tube internally recirculate dair lift biocontactor in comparison with the conventional shake flask batch adsorption equilibrium experiments. Binary protein mixtures contained bovine serum albumin (BSA) and bovine haemo...

The adsorption study was conducted on three Japanese soils with different soil properties to characterize the adsorption pattern of Arsenic (As). Double tube method was used to find out the effect of soil moisture levels on As adsorption. For this study, besides double tube method, conventional batch method also was used. The As adsorption showed two phase kinetics. An initial and rapid adsorpt...

U(VI) adsorption onto goethite-coated sand was studied in batch experiments ata solid-to-solution ratio (SSR) ranging from 33.3 to 333 g/L. Batch kinetic experiments revealed that the presence of 10(-4) M phosphate increased both the initial rate and ultimate extent of U(VI) adsorption compared with phosphate-free systems. Our experimental U(VI) adsorption isotherms were independent of SSR in p...