The cellular uptake of a series of dipyridophenazine (dppz) complexes of Ru(II) was examined by flow cytometry. The complexes, owing to their facile synthesis, stability, and luminescence, provide a route to compare and contrast systematically factors governing cellular entry. Substituting the ancillary ligands in the dppz complexes of Ru(II) permits variation in the overall complex charge, siz...

Complexes of OsO4 with 2,2'-bipyridine (Os,2,2'-bipy),4,4'-bipyridine (Os,4,4'-bipy), 1,10-phenanthroline (Os,phe), bathophenanthroline disulfonic acid (Os,bpds) and OsO4, pyridine reagent (Os,py) were used to probe structural distortions at the junctions between right-handed B and left-handed Z DNA in supercoiled plasmids pRW751 and pPK1 (both containing (dC-dG)13 and (dC-dG)16 segments). With...

The well-known methods for the determination of serum iron, which are based on colour reactions with bathophenanthroline disulfonate, Ferrozine® or Chromazurol B, require — even on a microscale — sample amounts between 0.1 and 1.0 nil of serum (1,2,3). These sample volumes are too large for paediatric purposes. Reduction of sample size is possible in flame atomic absorption spectrophotometry us...

An in-house Pressure Sensitive Paint (PSP) formulation has been developed at the Aero-Physics Laboratory at the University of Manchester. The PSP uses Bathophenanthroline Ruthenium as the luminophore molecule and is incorporated in a sol-gel matrix. Excitation occurs at 400-500 nm and emission at 550-650 nm. The Stern-Volmer plot of the PSP reveals small temperature dependence, which has always...

Five new [Pt(N^N)(dtoc)] complexes (1-5; N^N = diimine: 2,2'-bipyridine and its 4,4'-alkyl/aryl-substituted derivatives or 1,10-phenanthroline; dtoc(2-) = 1,2-dithiolate-1,2-closo-dicarbadodecaborane) have been synthesized and characterized by spectroscopic and electrochemical methods, and by means of X-ray diffraction in the case of complexes 1 and 4. Hybrid DFT and time-dependent (TD) DFT cal...

Palladium(II) complexes catalyze the formation of enamides via the formal cross-coupling reaction between nitrogen nucleophiles and vinyl ethers. These vinyl transfer reactions proceed in good yields with amide, carbamate, and sulfonamide nucleophiles, and the optimal catalyst is (DPP)Pd(OCOCF(3))(2) (DPP = 4,7-diphenyl-1,10-phenanthroline). [reaction: see text]

The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.

Methods are reported for the manual spectrophotometric or fluorometric estimation of tocopherol in human cerebrospinal fluid. The fluid is centrifuged, an equal volume of ethanol is added, and the tocopherol is extracted with hexane, which is then used for the direct estimation by fluorometry. The fluorescence of tocopherol is significantly affected by the proportion of ethanol in the hexane so...