Some pesticide chemicals are based on inorganic elements such as sulfur, copper (i.e. copper sulfate ‘Bordeaux mixture’, copper hydroxide, and copper oxychloride), and arsenic salts (i.e. lead arsenate, calcium arsenate, sodium arsenite), or they contain an inorganic element in their chemical structure such as the organometallic pesticides based on manganese dithiocarbamate (maneb), manganese a...

PURPOSE The sorption behavior of the herbicide 4-chloro-2-methylphenoxyacetic acid (MCPA) to three different artificial soil mixtures was investigated. Artificial soils serve as model systems for improving understanding of sorption phenomena. MATERIALS AND METHODS The soils consisted of quartz, ferrihydrite, illite, montmorillonite, and charcoal. In a previous study, several selected mixtures...

Mineralization potentials, rates, and kinetics of the three phenoxy acid (PA) herbicides, 2,4-dichlorophenoxyacetic acid (2,4-D), 4-chloro-2-methylphenoxyacetic acid (MCPA), and 2-(4-chloro-2-methylphenoxy)propanoic acid (MCPP), were investigated and compared in 15 soils collected from five continents. The mineralization patterns were fitted by zero/linear or exponential growth forms of the thr...

Flaxleaf fleabane is a difficult-to-control weed in dryland minimum tillage farming systems in the northeast grains region of Australia. Experiments were conducted between 2003 and 2005 to identify effective control strategies on flaxleaf fleabane in wheat and sorghum. A preplant application of chlorsulfuron at 15 g ai/ha in wheat controlled flaxleaf fleabane $ 90%. The efficacy of early postem...

BACKGROUND Subsurface transport via tile drains can significantly contribute to pesticide contamination of surface waters. The spatial variation in subsurface leaching of normally applied herbicides was examined together with phosphorus losses in 24 experimental plots with water sampled flow-proportionally. The study site was a flat, tile-drained area with 60% marine clay in the topsoil in sout...

2,4-dichlorophenoxyacetic acid (2,4-D) and 4-chloro-2-methylphenoxyacetic acid (MCPA) are active substances in many weed-killer agents commonly used for the protection of crops. The literature data accompanied by our former studies showed that in weak-acid and neutral environments these compounds react with bivalent metal ions and form complexes of limited solubility in water. It was assumed th...

field experiments were conducted in amirkabir sugarcane agro-industry (khuzestan province, iran) farms to evaluate the efficacy of integrated chemical and mechanical methods in controlling weeds. experiments were carried out in a split plot-randomized complete blocks design with four replications. the main plot consisted of four mechanical treatments, namely: hilling up, sweep cultivator, disc ...

A simple high-performance liquid-chromatographic assay for eight chlorophenoxy (2,4-D and related compounds) and two benzonitrile (bromoxynil and ioxynil) herbicides has been developed to aid in the diagnosis of acute poisoning. Sample (whole blood, plasma/serum, urine, or tissue homogenate) or standard (100 microL) is vortex-mixed (ca. 5 s) with 20 microL of internal standard solution [1.00 g/...

Photocatalytic remediation technology has been shown to be a favorable approach for the removal of range environmental pollutants in water treatment. While this can often achieve complete degradation, overlooked are reaction intermediates that potentially as harmful original parent compound. In case photocatalytic oxidation herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA), we have recently ...