A new photocurrent-generation system based on Ru(bpy)3(2+) (bpy=2,2'-bipyridine) tethered on phospholipid/alkanethiol hybrid bilayers in aqueous media is reported. The construction of such a system is straightforward. First, a self-assembled monolayer (SAM) of alkanethiol is formed on gold, and separately, liposomes containing Ru(bpy)3(2+)-conjugated dioleoylphosphoethanolamine (DOPE) are prepa...

A bromide–modified silver electrode is reported, in the present study, to catalyze the redox reactions of metalloproteins. This study describes that the bromide ions show very good redox behavior with silver electrode. The cathodic and anodic peak potentials were related to the concentration of bromide ions involved in making bromide-modified silver electrode. The electrode reaction in the brom...

Cu electrodeposition onto Ru during dual damascene processing is complicated by the possible presence of Ru oxide, which is known to exist at more cathodic potentials than predicted by its Pourbaix diagram. Several research groups have proposed cathodic treatments prior to Cu electrodeposition to reduce Ru oxide, but these methods were developed semiempirically. We report voltammetry and impeda...

There is a need for alternative catalysts for oxygen reduction in the cathodic compartment of a microbial fuel cell (MFC). In this study, we show that a bipolar membrane combined with ferric iron reduction on a graphite electrode is an efficient cathode system in MFCs. A flat plate MFC with graphite felt electrodes, a volume of 1.2 L and a projected surface area of 290 cm2 was operated in conti...

OBJECTIVE To assess the effect of high-voltage cathodic current on pain from a sciatica experimental model. METHODS A total of 16 male Wistar rats were submitted to the sciatica experimental model in the right hind paw. They were divided into sham group (GS) and group treated with cathodic current (GP-) for 20 min/daily, for 10 days). The model of sciatic compression was performed with a 4.0-...

The surface activity of xanthine (Xan) and xanthosine (Xano) at a hanging mercury drop electrode (HMDE) was studied using out-of-phase ac and cyclic dc voltammetry. The results show that Xan and Xano were strongly adsorbed and chemically interacted with the charged mercury surface, which is the prerequisite step for applying the cathodic adsorptive stripping voltammetric determination of such b...

The electrochemical behavior of passive Fe and thin, sputter-deposited films of Fe2O3 was studied in borate and phosphate buffer pH 8.4 solutions. Cyclic voltammograms and in situ light absorption measurements which enable the monitoring of the oxide film thickness indicate a similar behavior of the Fe electrode in both pH 8.4 solution, especially a presence of a oxide-free surface at low catho...

We report single-step vacuum growth of stoichiometric superconducting thin films of MgB2, using AASC’s cathodic arc deposition process. Energetic condensation using cathodic arcs produces non-equilibrium fast ions (~50-100eV) that allow growth modes on relatively low temperature substrates. We have demonstrated MgB2 films with Tc of 34K by depositing at 275 °C in a single step, from a stoichiom...

Microbial fuel cells (MFCs) are a promising green approach for wastewater treatment with the simultaneous advantage of energy production. Among the various limiting factors, the cathodic limitation, with respect to performance and cost, is one of the main obstacles to the practical applications of MFCs. Despite the high performance of platinum and other metal-based cathodes, their practical use...

Of the several factors which influence electrocatalytic activity, particle size and structural effects are of crucial importance, but their effects and mechanism of interaction, vis-a-vis overall performance, have been, at best, vaguely understood. The situation is further aggravated by the use of a wide range of experimental conditions resulting in non-comparable data. This paper attempts syst...