The electrochemical behavior of passive Fe and thin, sputter-deposited films of Fe2O3 was studied in borate and phosphate buffer pH 8.4 solutions. Cyclic voltammograms and in situ light absorption measurements which enable the monitoring of the oxide film thickness indicate a similar behavior of the Fe electrode in both pH 8.4 solution, especially a presence of a oxide-free surface at low catho...

We report single-step vacuum growth of stoichiometric superconducting thin films of MgB2, using AASC’s cathodic arc deposition process. Energetic condensation using cathodic arcs produces non-equilibrium fast ions (~50-100eV) that allow growth modes on relatively low temperature substrates. We have demonstrated MgB2 films with Tc of 34K by depositing at 275 °C in a single step, from a stoichiom...

Microbial fuel cells (MFCs) are a promising green approach for wastewater treatment with the simultaneous advantage of energy production. Among the various limiting factors, the cathodic limitation, with respect to performance and cost, is one of the main obstacles to the practical applications of MFCs. Despite the high performance of platinum and other metal-based cathodes, their practical use...

Of the several factors which influence electrocatalytic activity, particle size and structural effects are of crucial importance, but their effects and mechanism of interaction, vis-a-vis overall performance, have been, at best, vaguely understood. The situation is further aggravated by the use of a wide range of experimental conditions resulting in non-comparable data. This paper attempts syst...

A novel approach is suggested, using laser-induced shock wave measurements to estimate the effects of cathodic hydrogen charging on the mechanical properties and fracture characteristics of materials. This approach is applied to (1) determine the dominant mechanism of hydrogen embrittlement (HE) in an amorphous Fe80B11Si9 alloy; and (2) estimate the effects of the high pressures involved in cat...

A hyperspectral imaging method was developed that allowed the identification of heterogeneous plasmon response from 50 nm diameter gold colloidal particles on a conducting substrate in a transparent three-electrode spectroelectrochemical cell under non-Faradaic conditions. At cathodic potentials, we identified three distinct behaviors from different nanoparticles within the same sample: irrever...

Developing cheap electrocatalysts for cathodic oxygen reduction in neutral medium is a key factor for practical applications of microbial fuel cells (MFCs). Natural hematite was investigated as a low-cost cathode to improve the performance of microbial fuel cells (MFCs). With hematite-coated cathode, the cell current density stabilized at 330.66 ± 3.1 mA·m−2 (with a 1000 Ω load) over 10 days un...

Carbon-paste electrodes (CPEs) were studied to elucidate the cathodic stripping voltammetric determination of iodine. At an accumulation potential of 1.0 V (vs. SCE), iodide was preconcentrated on CPEs via an ion-pairing reaction, followed by oxidation to iodine. Then a linear scan voltammogram was recorded after 10 s of quiescent time by a cathodic potential scan from 0.7 V to 0.1 V at a scan ...

This research adopted the version control system into the model construction for the single chamber aircathode microbial fuel cell (MFC) system, to understand the interrelation of biological, chemical, and electrochemical reactions. The anodic steady state model was used to consider the chemical species diffusion and electric migration influence to the MFC performance. In the cathodic steady st...

Purpose: To investigate the electro-reduction behaviour and determination of ciprofloxacin using a hanging mercury drop electrode. Methods: Cyclic voltammograms of ciprofloxacin recorded in Britton – Robinson buffers pH 2 – 5 exhibit a single irreversible cathodic peak. The dependence of the peak current and peak potential values on buffer (nature, pH and concentration) and accumulation conditi...