Background Cerium oxide (CeO2) is a technologically important material due to its properties and applications in several areas that range from engineering to biological sciences. Despite the hydrothermal microwave method versatility, its crystallization kinetics has low speed when the processing temperatures are below 300°C which are the desired conditions for soft chemistry processes [1,2]. At...

We propose a model for the water-oxidation and recovery systems of the oxygen-evolving complex (OEC) of the photosystem II (PSII) enzyme. The whole system is constructed from two catalytic cycles, conducted as a tandem reaction: (i) a water-oxidation loop uses cerium(IV) ammonium nitrate as an oxidant to activate a dimanganese complex for water-oxidation and thereby liberate a molecule of O2 an...

objective: finding a suitable laboratory test that can diagnose schizophrenia in its early stages could be very important. according to the hypothesis of lack of noradrenalin balance in the brain, it is illustrated that the disorder severity has a negative correlation with the amount of urine noradrenalin metabolite [3-methoxy-4-hydroxy phenyl glycol (mhpg) sulfate]. in this research, instead o...

The present investigation assesses the application of ceric sulfate for the removal of the colorant reactive blue19 (R.B19) from synthetic wastewater. The adsorption characteristics and dye removal efficiency of adsorbent have been determined by investigating factors such as effect of pH (pHOptimum

in this research, a new technetium-99m generator has been developed with addition of cerium oxide to alumina column.  the adsorption behaviors of 99mo in the form of molybdate and 99mtc in the form of pertechnetate on ceo2/al2o3 was investigated and showed that the adsorption capacity of molybdate on this generator is higher than usual generator using al2o3. ceric ions were selected as an addit...

A simple, highly sensitive chemiluminescent method using flow injection is described for the determination of three substituted benzamides, namely: sulpiride, sultopride and tiapride. The method is based on the sensitizing effect of these drugs on the chemiluminometric oxidation of sulphite by cerium(IV). The different experimental parameters affecting the chemiluminescence intensity were caref...

[1] We use observations of the mass-independent oxygen isotopic composition (DO) of sulfate in the marine boundary layer (MBL) to quantify the sulfate source from aqueous SO2 (S(IV)) oxidation by O3 in alkaline sea-salt aerosols. Oxidation by O3 imparts a large DO signature to the resulting sulfate (8.8%) relative to oxidation by H2O2 (0.9%) or by OH or O2 (0%). Ship data from two Indian Ocean ...

In the paper, we claim to observe the optical activity of cerium in a triply doped yttrium oxide system displaying both upconverting and downshifting properties. The singly-doped Y2O3:Ce 3+ system has already been investigated by many groups, with controversial results, as stated in our paper. Some groups suggested an emission centered on cerium ions, while others proposed a defect-related emis...