Colloidal perovskite oxide nanocrystals have attracted a great deal of interest owing to the ability to tune physical properties by virtue of the nanoscale, and generate thin film structures under mild chemical conditions, relying on self-assembly or heterogeneous mixing. This is particularly true for ferroelectric/dielectric perovskite oxide materials, for which device applications cover piezo...

Silicon nanocrystals embedded in SiO2 were isolated with a selective etching procedure, and the isolated nanocrystals’ excitonic emission energy was studied during controlled oxidation. Nanocrystals having initial diameters, d0, of ,2.9–3.4 nm showed a photoluminescence sPLd blueshift upon oxidatively induced size reduction, as expected from models of quantum confinement. Oxidation of smaller S...

Levulinic acid (LA), 4-oxo-pentanoic acid, is a new platform chemical with various potential uses. In this paper, catalytic hydrogenation and oxidation of levulinic acid were studied. It was shown from experiments that levulinic acid can be hydrogenated to γ-valerolactone (GVL) over transition metal catalysts and oxidative-decarboxylated to 2-butanone (methyl-ethyl-ketone, MEK) and methyl-vinyl...

Herein, we report on nano-sized Mn oxide/carbon nanotubes, graphene and graphene oxide as water-oxidizing compounds in artificial photosynthesis. The composites are synthesized by different and simple procedures and characterized by a number of methods. The water-oxidizing activities of these composites are also considered in the presence of cerium(IV) ammonium nitrate. Some composites are effi...

Due to the increasing use of nanometric cerium oxide in applications, concerns about the toxicity of these particles have been raised and have resulted in a large number of studies. We report here on the interactions between 7 nm anionically charged cerium oxide particles and living mammalian cells. By a modification of the particle coating including low-molecular weight ligands and polymers, t...

We report a "ligand stripping" method for the creation of secondary structures of colloidal nanocrystals. Using iron oxide as an example, we demonstrate that the use of diols as "stripping agents" allows the controllable removal of the original capping ligands and induces aggregation of nanocrystals into well-defined clusters.

As an alternative to chromate conversion coatings, rare-earth coatings especially cerium, because of the low toxicity, have attracted considerable attention. Using dip immersion method, cerium-based conversion coating was deposited on aluminum 2024. Corrosion resistance was studied in 3.5 wt.% NaCl solution using potentiodynamic polarization, electrochemical impedance spectroscopy, and surface ...

In this paper, we present a method of generating nearly superhydrophobic surfaces from Femtosecond Laser Surface Processed (FLSP) metallic substrates and the study of their thermal stability at high temperatures. Using an FLSP process, hierarchical micro/nano structures were fabricated on stainless steel 316 after which a 200 nm Cerium Oxide (CeO2) film was sputtered onto the surface. Before Ce...

The study on physicochemical properties of maltodextrin-coated cerium oxide nanoparticles was carried out. surface structure and CeO 2 were investigated. ability to perform the functions catalase peroxidase enzymes, as well inactivate hydroxyl radicals shown. Keywords: nanoparticles, oxide, catalytic activity, antioxidant activity.