نتایج جستجو برای: chronoamperometry
تعداد نتایج: 514 فیلتر نتایج به سال:
Ahatcaet Factors involved in construction and utilization of an inexpensive, rapid-response potentiostat with 50 mA current capabilities are discussed. The potentiostat can be used with ancillary units, eg function generators, for a variety of rapid perturbation approaches, eg cyclic voltammetry at scan rates to 4000 V/s or greater, potential-step chronoamperometry with data acquisition after 4...
Methanol electrochemical oxidation in a direct methanol fuel cell (DMFC) is considered to be an efficient pathway for generating renewable energy with low pollutant emissions. NiO−CuO and Ni0.95Cr0.05O2+δ thin films were synthesized using simple dip-coating method tested the electro-oxidation of methanol. These electrocatalysts characterized by X-ray diffraction spectroscopy (XRD), photoelectro...
We synthesized polythiophene (PTh) films on stainless steel electrodes using chronoamperometry in boron trifluoride diethyl etherate (BFEE) electrolyte with anionic surfactants. The presence of the anionic surfactants in BFEE reduced the oxidation potential of thiophene and increased the oxidation current during electropolymerization. The measured in-plane electrical conductivity of PTh films s...
Different kind of macrosensors have been assembled using several nonconducting electropolymerized films. Different techniques of film electropolymerization such as cyclic voltammetry and chronoamperometry are compared. Film function, including the prevention of interferences and fouling problems and immobilization of the enzymes are described and optimised. We have immobilized oxidase [1] and d...
Cubic PtCu nanocages (NCs) were successfully synthesized through a redox reaction using cuprous oxide (Cu2O) as a sacrificial template and reducing agent. The porous PtCu NCs were composed of amounts of PtCu nanograins with an average particle size of 2.9 nm. The electrocatalytic performance of the PtCu NC electrode towards H2O2 was studied by cyclic voltammetry (CV) and chronoamperometry. The ...
Electrochemical systems are considered for which the concentration of ions in solution is low, and therefore there is an electric field which extends deep into solution away from the electrode surface. Finite difference methods are used to model a potential step chronoamperometry experiment at a microhemisphere electrode. Concentration profiles, potential profiles, and current-time curves are p...
A carbon paste electrode (CPE) chemically modified with 1-[4-(ferrocenyl ethynyl)phenyl]-1-ethanone (4-FEPEMCPE) was employed to study the electrocatalytic oxidation of L-cysteine using cyclic voltammetry, differential pulse voltammetry and double potential step chronoamperometry as diagnostic techniques. The diffusion coefficient (D = 7.863 x 10(-6) cm2 s(-1)) of L-cysteine was also estimated ...
BACKGROUND Bioimpedance is an electrical property of living tissue that has been shown to be a safe technique when used in a number of biomedical applications. The aim of this research was to assess the utility of bioimpedance measurement as a rapid, cost-effective, and noninvasive adjunct to digital rectal examination and PSA in differentiating tumor from normal prostatic tissue. METHODS Thr...
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