Dendrimer-templated nanoparticle synthesis is an efficient method for preparing a variety of monoand bimetallic nanomaterials, whose sizes are constrained by the loading capacity of the dendrimer template. A common commercially available dendrimer is composed of repeating amino-amide units (polyamidoamine, PAMAM), whose internal amines coordinate with free metal ions in solution. The metal ion ...

In this study, a novel solid dendrimer amine (hyperbranched polymers) was prepared using mesoporous carbon nitride functionalized by melamine based dendrimer amines. This adsorbent was denoted MDA-MCN-1. The process was stepwise synthesis and hard-templating method using mesoporous silica SBA-15 as a template. Cyanuric chloride and N,N-diisopropylethylamine (DIPEA, Merck) were used for function...

Novel copper phthalocyanine (CuPc) materials have potential applications in solar cells, fuel cells, optical-limiting materials, gas sensors and field-effect transistors. Most recently there have been interests in applications for high dielectric constant material for capacitors. For example, Zhang et al. have reported a dielectric constant of 48 at 1MHz in an electrostrictive polymeric CuPc/Po...

Platinum dendrimer-encapsulated nanoparticles (DENs) were prepared within fourth-generation, hydroxyl-terminated, poly(amidoamine) dendrimers and immobilized on glassy carbon electrodes using an electrochemical coupling strategy. X-ray photoelectron spectroscopy, electron microscopy, and electrochemical experiments confirmed that the Pt DENs were about 1.4 nm in diameter and that they remained ...

Dendrimer molecules and aggregates are chemical structures with regular branching that underlies their physicochemical properties. Regular dendrimers have been studied both theoretically experimentally, but the irregular intermediate between of neighboring generations not. In present work, dendrimer aggregates, intermediate, investigated in terms information entropy approach. As found, asymptot...

Efficient chromatography-free synthesis of a new example an aromatic dendrimer bearing nine ferrocene residues and its application in the detection 9,10-diphenylanthracene are reported.

The structure of copper(II) complexes formed with triethanolamine (TEA) core poly(amidoamine) (PAMAM) dendrimers from generation 0 (G0) to 4 (G4) were investigated by the electron paramagnetic resonance (EPR) technique and molecular simulations. Different square planar coordination modes were detected as a function of copper(II) concentration, whose dynamic evolution relates to the high structu...

Understanding the underlying mechanism of nanomedicine-biomembrane interactions is important for the design and optimization of payload delivery systems. This study investigates the interactions between polyamidoamine (PAMAM) dendrimer-paclitaxel conjugates and biomembranes using coarse-grained molecular dynamics simulations. We found that acidic conditions (e.g., pH ∼ 5) and membrane asymmetry...

Prion diseases are characterized by the accumulation of PrP(Sc), an aberrantly folded isoform of the host protein PrP(C). Specific forms of synthetic molecules known as dendrimers are able to eliminate protease-resistant PrP(Sc) in both an intracellular and in vitro setting. The properties of a dendrimer which govern this ability are unknown. We addressed the issue by comparing the in vitro ant...

We report that dendrimer-encapsulated Pd nanoparticles having a diameter of approximately 1.7 nm are effective and general catalysts for coupling aryl halides to organostannanes (the Stille reaction) under mild conditions. The significant results of this study are that the Stille reaction is catalyzed by dendrimer-encapsulated Pd nanoparticles in very good yield, in aqueous solution at 23 degre...