نتایج جستجو برای: electrodeposition kinetics

تعداد نتایج: 100936  

2007
C. T. J. Low E. P. L. Roberts F. C. Walsh

Numerical simulations of the non-uniform current, potential and concentration distributions along the cathode of a rotating cylinder Hull (RCH) ell (RotaHull® cell) are performed using finite element methods. Copper electrodeposition from an acid sulfate electrolyte is used as a test system. rimary, secondary and tertiary current distributions are examined. The importance of controllable and un...

2008
Stephen Maldonado Nathan S. Lewis

n-Si/Cd and n-Si/Pb Schottky junctions have been prepared by electrodeposition of Cd or Pb from acidic aqueous solutions onto H-terminated and CH3-terminated n-type Si 111 surfaces. For both nondegenerately nand degenerately n+doped H–Si 111 electrodes, Cd and Pb were readily electroplated and oxidatively stripped, consistent with a small barrier height b at the Si/solution and the Si/metal jun...

Electrodeposition of CuInSe2 (CIS) and CuInAlSe2 (CIAS) from aqueous solution has been systematically investigated by cyclic voltammetery implementing different scan rates. It has been shown that electrodeposited CIS and CIAS have been formed on the substrate through electrochemical-chemical interaction of reduces species on the substrate.  From the obtained results, it could be inferred that I...

2015
Junjie Wang Hui Zhou Jagjit Nanda Paul V. Braun

Ni scaffolded mesostructured 3D Fe2O3 electrodes were fabricated by colloidal templating and pulsed electrodeposition. The scaffold provided short pathways for both lithium ions and electrons in the active phase, enabling fast kinetics and thus a high power density. The scaffold also resulted in a reduced voltage hysteresis. The electrode showed a reversible capacity of ∼1000 mAh g−1 at 0.2 A g...

Journal: :The journal of physical chemistry. B 2005
Jeong-Mi Moon Alexander Wei

Monolithic Au nanorod arrays can be grown by electrodeposition in Au-backed nanoporous alumina templates using polyethylenimine (PEI) as an adhesion layer, with excellent height control between 300 nm and 1.4 microm. The local height distribution can be extremely narrow with relative standard deviations well below 2%. The uniform growth rate appears to be determined by the adsorbed PEI matrix, ...

2018
Ping Wang Xiao Lin Bo Yang Jia-Mei Jin Christopher Hardacre Neng-Fei Yu Shi-Gang Sun Wen-Feng Lin Gang Sun

Tetrahexahedral Pd nanocrystals (THH Pd NCs) were prepared on a glassy carbon electrode using a programmed square-wave potential electrodeposition method, and modified by Bi adatoms with a range of coverages via the cyclic voltammetry method. The reactivity of the catalysts prepared towards ethanol electrooxidation reaction (EOR) was studied in alkaline medium at various temperatures and under ...

Journal: :Langmuir : the ACS journal of surfaces and colloids 2006
Kyoungja Seo Eric Borguet

A write, read, and erase nanolithographic method, combining in situ electrodeposition of metal nanostructures with atomic force microscopy (AFM) nanoshaving of a 1-hexadecanethiol (HDT) self-assembled monolayer (SAM) on Au(111) in an aqueous solution, is reported. The AFM tip defines the local positioning of nanotemplates via the irreversible removal of HDT molecules. Nanotemplates with lateral...

Journal: :IBM Journal of Research and Development 2005
Thomas P. Moffat Daniel Wheeler Monica D. Edelstein Daniel Josell

Superconformal electrodeposition of copper is explained by the recently developed curvature-enhanced-accelerator coverage (CEAC) model, which is based on the assumptions that 1) the local growth velocity is proportional to the surface coverage of the accelerator, or catalyst, and 2) the catalyst remains segregated at the metal/electrolyte interface during copper deposition. For growth on nonpla...

Journal: :Metals 2021

Terpyridine-functionalized Ti nanospike electrodes (TiNS-SiTpy) were developed and applied to cyclic voltammetry amperometry of Ln (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) ions mixed Eu (III) + in a 0.1 M NaClO4 electrolyte. Electrodeposition was successfully performed over TiNS-SiTpy electrodes, which fully examined by scanning electron microscopy, X-ray diffraction crystallography...

Journal: :Electrochimica Acta 2021

Physicochemical and electrochemical properties of N,N,N-dimethylbutylammonium methanesulfonate, [DMBA][MS], ionic liquid (IL) have been determined, the potential application for recovery lead from lead-acid batteries is discussed. To optimise transport IL, dependences were measured conductivity, density viscosity with varying amounts excess acid water as a diluent in electrolyte mixture. Molar ...

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