background: heat stress evaluation and timely notification, especially using meteorological data is an important issue attracted attention in recent years. therefore, this study aimed at answering the following research questions: 1) can enthalpy as a common environmental parameter reported by meteorological agencies be applied accurately for evaluation of thermal condition of outdoor settings,...

The complexation reaction between 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (Kryptofix5) ligand with Zn2+, Ni2+, Co2+, Pb2+, Mn2+ and Cu2+ ions were studied conductometrically in different AcetoNitrile-NitroMethane (AN-NM) and AcetoNitrile-Methanol (AN-MeOH) mixtures. The formation constants of the resulting...

Because water dissolves in silicate melts as at least two species, H O molecules and OH groups, the exsolution 2 Ž . evaporation enthalpy of the H O component from a silicate melt depends on species proportions, which in turn depends on 2 H O pressure. In this short communication, a formal analysis of the exsolution enthalpy of water from a silicate melt is 2 presented, taking into account of t...

Abstract Recently, one of the authors suggested calculating void fraction, an essential element in thermalhydraulics, working with the ‘thermodynamic’ quality instead of the usual ‘flow’ quality. However, the standard heat balance is currently stated as a function of the ‘flow’ quality. Therefore, we should search a new energy balance between the mixture enthalpy, based on ‘thermodynamic’ quali...

Starch and proteins are major components in the wheat endosperm that affect its end product quality. Between the two textural classes of wheat i.e. hard and soft, starch granules are loosely bound with the lipids and proteins in soft wheat due to higher expression of interfering grain softness proteins. It might have impact on starch granules properties. In this work for the first time the phys...

Current Isothermal Titration Calorimetry (ITC) data in the literature have relatively high errors in the measured enthalpies of protein-ligand binding reactions. There is a need for universal validation standards for titration calorimeters. Several inorganic salt co-precipitation and buffer protonation reactions have been suggested as possible enthalpy standards. The performances of several com...

Additives to polymeric materials can lead to appreciable changes in the rates of relaxation and reaction in these mixtures that can profoundly alter material properties and function. We develop a general theoretical framework for quantifying changes in the "high-frequency" relaxation dynamics of mixtures based on classical transition state theory, in conjunction with mathematical statements reg...

During the past year the activities of the Chemical Thermodynamics Data Center and the JANAF Thermochemical Tables project have been combined to obtain an extensive collection of thermodynamic information for many chemical species, including the elements. Currently available are extensive bibliographic collections and data files of heat capacity, enthalpy, vapor pressure, phase transitions, etc...

the formation of ice on a cold surface and its shape, play an important role in some of the various problems. the position of solid surface of ice accretion, its growth shape and the effect of liquid phase on it, are important parameters in the various applications. difficulty of analytic techniques and expensive of experimental methods encourage the numerical modeling procedures in the investi...