Epoxy powder coatings containing zinc aluminum phosphate (ZAP) and zinc phosphate (ZP), which are the 2nd and 1st generation of phosphate-based pigments respectively, were applied to the surface of mild steel sheets. The anticorrosive performances of the coated samples were studied using electrochemical impedance spectroscopy (EIS). Cathodic disbonding resistance and the adhesion performance of...

In this communication, a bis-silane prepolymer was used to modify epoxy resin, aiming enhance the corrosion resistance of coatings on aluminum alloy substrates. The prepared by tetraethoxysilane (TEOS) and γ-glycidoxypropyl trimethoxysilane (GPTMS). behavior silane-epoxy studied. Compared with silane monomer-modified coatings, bis-silane-modified have lower coating capacitance (Cc), higher char...

Isocyanate-free cathodic ED coatings. Most of the resins used in the cathodic electrodeposition (CED) coatings are made from modified epoxy resin and blocked polyisocyanate in which the crosslinking is achieved by polyurethane and polyurea formation. A resin system has been developed that is isocyanate free and avoids not only the toxicity aspect, but also, to a great extent, the weight loss of...

The idea of smart inhibitors is based on the principle that an inhibitor is used where needed. This will reduce the use of inhibitors and protect materials in hostile environments. On the other hand, direct addition of the inhibitor within the coating can be harmful, resulting in the loss of inhibitors ability, deterioration in the coating or both of them. An appropriate method for solving thes...

This work reports the self-healing behavior of epoxy-based double-layer nanocomposite coatings designed to mitigate corrosion in various industrial applications. Zirconia (ZrO2) nanoparticles were used as a carrier load separately agent, polyethyleneimine (PEI), and inhibitor, imidazole (IM). The loaded ZrO2 with IM PEI doped into epoxy matrix applied on polished steel substrate form pre top la...

Polymer-clay nanocomposite coatings have attracted much attention because of impressive enhancements of coating properties. In this research, both commercially available and isophoronediamine-modified montmorillonite clays were used to obtain epoxy-clay nanocomposite coatings. These nanocomposite materials with different clay loadings in the form of coatings were applied to cold-rolled steel (C...

In this research, the synthesis and application of vitrimer epoxy coatings for long-term corrosion protection metal surfaces are described. To that end, a polyamine curing agent based on vinylogous urethanes (VUs) was developed to add repairability, recyclability recoatability thermosetting materials. Thin films with excellent resistance water penetration damage could be obtained by combining d...