نتایج جستجو برای: equilibrium constant

تعداد نتایج: 338220  

ابراهیم, هاجر, علی اکبری, محمد,

We use gauge-gravity duality to study the effect of corrections to the coupling constant on equilibration time in field theory for scalar operators with Delta=2,3. We will show that for larger correction in coupling constant the equilibration time enhances and this behavior is independent of the method we use to make the system out of equilibrium. Interestingly we observe that for fast energy i...

The water relations play a fundamental role in seed comprehension of biology. In order to describe the process of drying and the effect on water activity, which controls biological change in storage, a sound knowledge of the relationship between equilibrium moisture content (EMC) and water activity/equilibrium relative humidity (ERH) is essential. The relationship between the total moisture con...

زارع, سمیه, عبادی, زهرا, میرزا, بهروز,

Recently the Jarzynski equation have been under many investigations. In this equation a relation between the average exponential of the work done on a system under non-equilibrium condition and equilibrium free energy differences is established. In different papers the equation has already been extended to different conditions. In this paper we will extend it to a situation that a system is dri...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 1978
T R Hays S H Lin H Eyring

The membrane model previously described [Hays, T.R., Buckwalter, C.Q., Lin S.H. & Eyring, H. (1978) Proc. Natl. Acad. Sci. USA 75, 1612-1615] for ion flow through a membrane is expanded to include the effect of binding of the mobile ion at the occupiable sites in the membrane. Two different effects were investigated: alteration of the association-dissociation rates at constant equilibrium const...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه پیام نور - دانشگاه پیام نور استان خراسان رضوی - دانشکده شیمی 1388

در این کار تحقیقاتی ابتدا مطالعه سینتیک واکنش پیریدین و 2 کلر پیریدین با کمپلکس پلاتین (ii) به فرمول p-tol)2 (sme2)2])pt]در دماهای 30،20،15،5 و 40 درجه سلسیوس بررسی گردید. که بدلیل سرعت زیاد واکنش محاسبه پارامترهای سینتیکی غیر میسر بود لذا کار ترمودینامیکی جانشینی سه لیگاند از پیریدین و مشتقات آن (2 کلروپیریدین و 2 برموپیریدین) در سه حلال (دی کلرو متان، استن و متانول) در دستور کار قرار گرفت. ب...

The water relations play a fundamental role in seed comprehension of biology. In order to describe the process of drying and the effect on water activity, which controls biological change in storage, a sound knowledge of the relationship between equilibrium moisture content (EMC) and water activity/equilibrium relative humidity (ERH) is essential. The relationship between the total moisture con...

Journal: :The journal of physical chemistry. B 2015
Arne Walter Martin Andresen Stefan Jakobs Jörg Schroeder Dirk Schwarzer

The reversible photoswitching of the photochromic fluorescent protein Padron0.9 involves a cis-trans isomerization of the chromophore. Both isomers are subjected to a protonation equilibrium between a neutral and a deprotonated form. The observed pH dependent absorption spectra require at least two protonating groups in the chromophore environment modulating its proton affinity. Using femtoseco...

Journal: :The Journal of the Society of Chemical Industry, Japan 1970

Journal: :نشریه دانشکده فنی 0
محمد مهدی منتظر رحمتی شهرام اسلامی

the srk two-parameter cubic equation of state has been used for the calculation of the equilibrium constant using the liquid and vapor fugacity coefficients for three binary mixtures. dew and bubble points have been determined using the equilibrium constants and the phase envelope has been plotted showing dearly that retrograde condenstaion occurs. the following percent deviations have been obt...

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