Size and shape-selective Sn(MoO4)2 nanomaterials have been synthesized for the first time using a simple hydrothermal route by the reaction of Sn(ii) chloride salt with sodium molybdate in CTAB micellar media under stirring at 60 °C temperature for about three hours. Needle-like and flake-like Sn(MoO4)2 nanomaterials were synthesized by optimizing the CTAB to metal salt molar ratio and by contr...

Reductive alkylation of three graphite starting materials G(flake), G(powder), and G(spherical) reveals pronounced differences in the obtained covalently functionalized graphene with respect to the degree of functionalization, exfoliation efficiency and product homogeneity, as demonstrated by statistical Raman microscopy (SRM), TGA/MS, IR-spectroscopy and solubility behavior.

Co(III) polyamine complexes with either two or three labile coordination sites bind strongly to high surface area metal oxides such as goethite or aluminium trihydroxide, and have been shown to act as passivating agents for aluminium flake in aqueous media, in addition to providing a potential method for surface functionalisation.

Strong quantization effects and tuneable near-infrared photoluminescence emission are reported in mechanically exfoliated crystals of γ-rhombohedral semiconducting InSe. The optical properties of InSe nanosheets differ qualitatively from those reported recently for exfoliated transition metal dichalcogenides and indicate a crossover from a direct to an indirect band gap semiconductor when the I...

Efficient visible light-induced photoelectrochemical oxidation of water was achieved using a tungsten(iv) oxide (WO(3)) film composed of perpendicularly oriented plate-like crystallites, a flake-wall film, prepared on a transparent conductive substrate by controlling anisotropic crystal growth of tungsten oxide hydrate (WO(3).H(2)O) followed by calcination.

We present here the results of a technological and typological analysis of the Acheulian and early Middle Paleolithic assemblages from Torre in Pietra (Latium, Italy) together with comparisons with the Acheulian small tools of Castel di Guido. The assemblages were never chronometrically dated before. We have now 40Ar/39Ar dates and ESR-U-series dates, within a geomorphological framework, which ...

Digesta and tissue samples were collected from the intestinal tracts of 27 pigs to determine the relationship between intestinal morphology and the utilization of nutrients from soybean flakes. Soybean flake treatments were under-, intermediate- and over-processed (i.e., 5, 20 and 60 min of autoclaving) either without extraction or with heating before or after extraction with a 55% ethanol-wate...

Large-flake graphene membranes up to 300 microm(2) can be exfoliated from graphite by oleyl amine based on solvothermal conditions. The exfoliated graphene sheets are of high quality and have few defects. The graphene dispersion, predominantly composed of monolayer graphene, had a high concentration of 0.15 mg ml(-1), and can be stabilized against re-aggregation.

The thermal conductivity of doped graphene flake of finite size is investigated with emphasis on the influence of the mass of the substituting atoms on this property. It is shown that graphene doping by small concentrations of relatively heavy atoms results in a disproportionately large drop in lattice thermal conductivity.

This paper combines individual-level data from the German Socio-Economic Panel (SOEP) with economic and demographic postcode-level data from administrative records to analyze the eff ects of immigration on wages and unemployment probabilities of highand low-skilled natives. Employing an instrumental variable strategy and utilizing the variation in the population share of foreigners across regio...