An experimental study on pressure evolution during closed vessel explosions of several gaseous fuel-air mixtures was performed, at various initial pressures within 0.3-1.2 bar and ambient initial temperature. Explosion pressures and explosion times are reported for methane-, n-pentane-, n-hexane-, propene-, butene-, butadiene-, cyclohexane- and benzene-air mixtures. The explosion pressures meas...

This article presents a new correlative model for surface tension of mixtures. This model is an extension of a predictive model recently proposed by our group. Other correlative models were evaluated and compared to the proposed model. Hydrocarbons mixtures exhibiting chemical nature or shape and chain size asymmetries were chosen as the standard to test the performance of the chosen models at ...

Low hydrocarbon concentrations stimulated the growth of Tetraselmis suecica, whereas higher concentrations (200 ppm) inhibited growth. The content of chlorophyll a in this microalga was affected in a similar way. Crude oil had the most marked effects. Dispersant SEAKLIN-101-NT and mixtures of oil and SEAKLIN-101-NT did not show selective toxicity for the microalga, although inhibitory effects c...

Using the G-Scheme, we have developed a specific procedure to generate simplified mechanisms for chemical kinetics processes, to analyze them in order to understand the role of the most important reactions, and to identify the most important reactions paths of the processes. The procedure is based on participation indices specifically created for a GScheme generated database. The effectiveness ...

Liquids like gasoline comprise a mixture of hundreds of hydrocarbon components. Gas chromatography of these complex mixtures produces highly detailed chromatograms that are characteristic of a particular sample. Although many of the volatile components will be lost during the fire, sufficient less-volatile components may have been left in partially burned wood or other materials to enable the d...

We present a method for the decomposition of the mass spectra of mixed gases using Bayesian probability theory. The method works without any calibration measurement and therefore applies also to the analysis of spectra containing unstable species. For the example of mixtures of three different hydrocarbon gases the algorithm provides concentrations and cracking coefficients of each mixture comp...

This paper proposes a novel use of the reciprocal calculation procedure (RCP) to calculate workplace emergency action levels (WEALs) for accidental releases of hydrocarbon mixtures. WEALs are defined here as the concentration in air that area monitors should alarm at to provide adequate warning and be sufficiently protective of health to allow at least enough time to don respiratory protective ...

A study of detonations in high-molecular weight hydrocarbon fuels of interest to pulse detonation engine applications was performed in a 280 mm diameter, 7.3 m long facility. Detonation pressure, wave speed, and cell width measurements were made in JP-10 mixtures and in mixtures representative of the decomposition products of JP-10. Experiments were performed in vapor-phase JP-10 mixtures at 35...