The adhesion of supported polymer thin fi lms is predominantly infl uenced by the substrate-fi lm interfacial properties. Utilizing steered molecular dynamics simulations, here we uncover that the cohesive noncovalent forces between polymer chains in the fi lm also have a signifi cant effect on the adhesive properties of supported fi lm. We demonstrate that weaker interchain interactions, all e...

Ozone modification method and air-oxidation were used for the surface treatment of polyacrylonitrile(PAN)-based carbon fiber. The surface characteristics of carbon fibers were characterized by X-ray photoelectron spectroscopy (XPS). The interfacial properties of carbon fiber reinforced polyamide 6 (CF/PA6) composites were investigated by means of the single fiber pull-out tests. As a result...

We propose a method for approximating the adhesion parameters in the Shan and Chen multicomponent, multiphase lattice Boltzmann model that leads to the desired fluid-solid contact angle. The method is a straightforward application of Young's equation with substitution of the Shan and Chen cohesion parameter and a density factor for the fluid-fluid interfacial tension, and the adhesion parameter...

The rough integument of water-walking arthropods is well known to be responsible for their water-repellency [1, 2, 3, 4]; however, water-repellent surfaces generally experience reduced traction at an air-water interface [5, 6, 7, 8]. A conundrum then arises as to how such creatures generate significant propulsive forces while retaining their water-repellency. We here demonstrate through a serie...

We examine the relative stability and adhesion of nonstoichiometric (polar) Al/WC interfaces and WC(0001) surfaces using Density Functional Theory as implemented in a planewave, pseudopotential formalism. Relaxed atomic geometries and the ideal work of adhesion were calculated for six different interfacial structures, taking into account both Wand C-terminations of the carbide. Based on the sur...

A tensile mechanical test suitable to measure the adhesion between brittle coatings and ductile substrates was applied to measure the adhesion of painted layers on polypropylene blends. The test involves the tensile deformation of the painted assembly, resulting in the periodic cracking of the brittle coating on the ductile substrate. The interfacial shear strength was determined by measuring t...

The adhesion of PACVD TiN films on tool steel ( AISI Pa ) has been investigated as a function of interfacial chemistry and the metallic interlayer formation between TiN films and substrate steel. Prior to TiN deposition, thin metallic interlayers such as T i , Cr, Cu films were deposited on a steel substrate with thickness range of 200 2000 A by Magnetron qxtterhg. TiN films were deposited by R...

The adhesion process of osteoblast-like cells on hydroxyapatite (HAp) and oxidized polystyrene (PSox) was investigated using a quartz crystal microbalance with dissipation (QCM-D), confocal laser scanning microscope (CLSM), and atomic force microscope (AFM) techniques in order to clarify the interfacial phenomena between the surfaces and cells. The interfacial viscoelastic properties (shear vis...

Interfacial compatibility of dissimilar materials was investigated to achieve a better understanding of interfacial adhesion in metal/polymer/metal systems. Surface modifications of polymers were applied to improve the adhesion. The modified surfaces were characterised by scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and contact angle ...