Pressure-driven and temperature-driven transitions of two thermoresponsive polymers, poly(N-isopropylacrylamide) (pNIPAM) and poly(N-vinylisobutyramide) (pNVIBA)), in both a soluble linear polymer form and a cross-linked hydro-gel form, were examined by a dynamic light-scattering method and direct microscopic observation, respectively. Their behavior was compared with that of protein systems. C...

The solution behaviors and microstructures of poly(N-isopropylacrylamide)x-poly(ethylene oxide)20-poly(propylene oxide)70-poly(ethylene oxide)20-poly(N-isopropylacrylamide)x (PNIPAmx-PEO20-PPO70-PEO20-PNIPAmx or PNIPAmx-P123-PNIPAmx) pentablock terpolymers with various PNIPAm block lengths in dilute and concentrated aqueous solutions were investigated by micro-differential scanning calorimetry ...

In order to introduce alternative functions into mammalian cells and control them under ambient conditions, poly(N-isopropyl acrylamide) (PNIPAM) was immobilized on the cell surface. Cellular aggregation could be regulated by temperature change. In addition, separation of PNIPAM-conjugated glycoproteins was successfully performed.

A novel method to fabricate shape controllable alginate/pNIPAAm complex microgels is reported. Monodisperse alginate/pNIPAAm droplets are created via microfluidics and cross-linked in different concentrations of hot glycerol/barium acetate water solutions. By changing the initial droplet size and glycerol concentration of the collecting solution, the resultant microgel shape and surface details...

A novel ion-responsive photonic hydrogel sensor based on the poly( N -isopropylacrylamide- co -benzo-18-crown-6-acrylamide) with fixed Fe 3 O 4 CNC chains has been developed for highly-selective, portable, visual detection and removal of Pb 2+ in water.

Switchable surface structures based on hydrogels are an emerging field in material science, microfluidics, soft robotics and anti-fouling. Here, we describe a novel method that uses a photo-cross-linkable terpolymer to create a hydrogel coating with a switchable surface structure. The terpolymer is based on poly(N-isopropylacrylamide) (PNIPAm) and it is shown that simple coating technologies li...

In this communication, a novel one-pot synthetic strategy for preparing hollow PNIPAM microspheres via an interfacial polymerization approach at the interface of an inverse W/O emulsion has been proposed and demonstrated. The results show that the prepared PNIPAM microspheres have real empty core and polymer shell structure, with a size range of 1-3 mum. The hollow microspheres experienced a re...