Label-free methods for evaluating lectin-cell binding have been developed to determine the lectin-carbohydrate interactions in the context of cell-surface oligosaccharides. In the present study, mass loading and electrochemical transducer signals were compared to characterize the interaction between lectin and cellular membranes by measuring the equilibrium association constant, Ka , between Ar...

Three isotherm models were used to describe adsorption equilibrium of a toxic chemical compound, phenol, onto a non porous adsorbent (Mediterranean Posidonia oceanica fibres) and a porous adsorbent, activated carbon prepared from Caribbean Vetiveria zizanoides roots. The adsorption characteristic parameters obtained were calculated using classical adsorption isotherm, i.e. the Langmuir (LI), Fr...

The aim of this paper is to investigate the removal of toluene from gaseous solution through Glycyrrhiza glabra root (GGR) as a waste material. The batch adsorption experiments were conducted at various conditions including contact time, adsorbate concentration, humidity, and temperature. The adsorption capacity was increased by raising the sorbent humidity up to 50 percent. The adsorption of t...

This commentary reports on a recent scientific study reported in this journal (cf. Molecules 2015, 20(3), 3565-3581). Some key scientific issues that require further explanation and clarification in the former article are as follows: (i) the relationship between the inclusion site accessibility and the level of cross-linking employed are brought into question for the case of α-CD and β-CD cross...

This paper reports on the direct ability of two positively charged organic polyelectrolytes (natural-based and synthetic) to reduce the atrazine concentration in water. The adsorption study was set up using multiple glass vessels with different polymer dosing levels followed by ultrafiltration with a 1 kDa membrane. The addition of polymers exhibited a capability in reducing the atrazine concen...

Waste materials with no further treatment such as orange barks from commercial oranges may act as adsorbent for the removal of Pb. Batch kinetic and equilibrium experiments were conducted to study the effects of contact time, initial pH, adsorbent dose and initial concentration of lead. The results show that the equilibrium was achieved less than 30 min of contact time. Three adsorption isother...

The interaction of (perfluorooctyl)nonanol (F8H9OH) with dipalmitoylphosphatidylcholine (DPPC) was systematically studied in two-component monolayers at air-water interface. The thermodynamic property and phase morphology of the monolayers were investigated by isotherm measurements and several microscopic methods such as Brewster angle microscopy, fluorescence microscopy, and atomic force micro...

We investigated the sorption of pentachlorophenol (PCP) to a surfactant-modified clay and the solubility of PCP as a function of pH and ionic strength. Pentachlorophenol is a hydrophobic ionizable organic compound; therefore, it can exist as either a protonated or adeprotonated species. The objectives of this study were to determine differences in the sorption and solubility of the two species ...

The present work was conducted for the synthesis of nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI)) removal as a highly toxic pollutant by using this nanoparticles. Batch experiments were performed to investigate the effects of Cr(VI), nZVI concentration, pH of solution and contact time variation on the removal efficiency of Cr(VI). nZVI was synthesized by reduction of ferric ...

This work reports the synthesis and characterization of a hybrid molecularly imprinted polymer (MIP) membrane for removal of methylene blue (MB) in an aqueous environment. MB-MIP powders were hybridized into a polymer membrane (cellulose acetate (CA) and polysulfone (PSf)) after it was ground and sieved (using 90 µm sieve). MB-MIP membranes were prepared using a phase inversion process. The MB-...