Using grand canonical Monte Carlo simulation we show, for the first time, the influence of the carbon porosity and surface oxidation on the parameters of the Dubinin-Astakhov (DA) adsorption isotherm equation. We conclude that upon carbon surface oxidation, the adsorption decreases for all carbons studied. Moreover, the parameters of the DA model depend on the number of surface oxygen groups. T...

The ability of coconut husk to remove methylene blue from solution was investigated. Factors such as initial dye concentration, contact time, adsorbent dosage and pH of solution were studied. Results show that Langmuir isotherm can be successfully applied to the methylede blue coconut husk system and that coconut husk is a suitable adsorbent for such a dye. Maximum adsorption capacity is 99 mg ...

This study explored the feasibility of using granular ferric hydroxide as adsorbent for the removal of NO3-N. Optimum conditions for NO3-N removal were found to be pH 5.0 and equilibrium time 80min. The equilibrium sorption isotherm was better described by Langmuir sorption isotherm model. The maximum sorption capacity of granular ferric hydroxide was 4.254mg/g at 298K. A comparison of four kin...

in this study, the adsorption of thallium (iii) ion from aqueous solutions onto modified znonanopowder as a fairly low cost adsorbent has been investigated in batch mode. it was found thatmodification of the adsorbent was essential for obtaining the significant adsorption percentage. theadsorbent modified by sodium phosphate solution. the effect of experimental parameters such asinitial ph of s...

We report an investigation of water adsorption in the hydrophobic metal-organic framework Al(OH)(1,4-naphthalenedicarboxylate) by means of molecular simulation. We show how simple molecular models allow us to reproduce the experimental isotherm, and how grand canonical Monte Carlo simulations can help elucidate the question of the thermodynamic nature of the adsorption transition, which turns o...

Recently, a new simple method for the purification of CdSe-CdS-ZnS quantum dots by using membrane filtration, the filtration process, successfully separated the oleic acid from quantum dots through membranes purification after synthesis; purification of quantum dots is a very significant part of post synthetical treatment that determines the properties of the material. We explore the possibilit...

the recovery and removal of the most organic acids in liquid solutions is usually treated with fixed-bed adsorption processes. among many adsorbents, granular activated carbon (gac) is used to remove organic pollutants such as benzoic acid (ba) from wastewaters conventionally. in this research, adsorption isotherm curves of ba onto gac at varying temperatures 25-60 °c are developed and the amou...

The effect of molecular weight on the crystallization behavior poly(lactic acid) (PLA) both isothermally and non-isothermally was studied using differential scanning calorimetry polarized optical microscopy. Two distinct crystal forms (? ??) were investigated under normal conditions for different weights. Using microscopy, growth rate spherulites measured nucleation estimated. Heterogeneous mor...

Analytical ultracentrifugation is one of the classical techniques for the study of protein interactions and protein self-association. Recent instrumental and computational developments have significantly enhanced this methodology. In this paper, new tools for the analysis of protein self-association by sedimentation velocity are developed, their statistical properties are examined, and consider...