an ion imprinted polymer (iip) based on aniline-formaldehyde was synthesized and then modified with extra aniline as cross-linker in the presence and absence of sr (ii) as the template to produce ion imprinted poly(aniline-formaldehyde) (iipaf) and non imprinted poly(aniline-formaldehyde) (nipaf). the sorbent was characterized by fourier transform infrared spectroscopy and was used for solid ph...

in this study, the potential of biosorbent obtained from silk maze, was investigated for the batch biosorption of direct red 81 (dr 81) in aqueous solution. the effects of temperature, biosorbent amount, contact time, initial dye concentration and ultrasonic irradiation were also evaluated. furthermore, experimental equilibrium and kinetics data were fitted by langmuir and freundlich isotherms ...

in this work, the potential of auto-ignition of heavy oil during in-situ combustion (isc) process was studied. kinetic studies were carried out using thermo gravimetric analyzer (tga), differential scanning calorimetry (dsc) and accelerating rate calorimetric (arc) techniques. effects of oxygen partial pressure, reservoir pressure and clay on auto ignition condition were investigated on a numbe...

graphene, a new member of the carbon family, was used as an adsorbent due to its exceptional capability to remove rhodamine b (rb) and malachite green (mg), two organic dyes, from aqueous solutions. adsorption kinetics of rb and mg onto graphene and adsorption capacity of the adsorbent were studied. also the effects of parameters, including ph, contact time, temperature, and adsorbent dosage we...

the automobile industry’s wastewater not only contains high levels of suspended and total solids such as oil, grease, dyestuff, chromium, phosphate in washing products, and coloring, at various stages of chassis manufacturing but also, a significant amount of dissolved organics,resulting in high bod or cod loads. suspended solids can be removed from the wastewater by chemical precipitation. h...

in atom transfer radical polymerization (atrp) of methyl acrylate (ma) with polyvinyl acetate macroinitiator in bulk at 90°c the plots of ln [m]0/[m] increased linearly with reaction time. the apparent propagation rate constant (kp app) of the reaction was obtained from the linear curve and used to calculate the free macroradical concentration ([r°]) in polymerization medium. the [r°] and also ...

in current work a comprehensive mechanism based on intermediate radical termination theory is assumed for raft polymerization of styrene over cumyl dithiobenzoate as raft agent. rate constants for addition (ka) and fragmentation reactions (kf) are set to 6×106 and 5×104 respectively, which lead to an equilibrium constant value of k = ka/kf = 1.2 x 102. moment equations method was used to model ...

kinetic study of epoxidation of unsaturated ketone of mesityl oxide was studied by usinghydrogen peroxide in the presence of dodecyltrimethyl ammonium bromide (dtab) as aninverse phase transfer catalyst. the reaction was carried out in the two-phase media of waterheptanewith 1:1 ratio in 25 °c. it was found that the order of reaction for mesityl oxide forketone concentration in the range of 0.0...

attempts to obtain experimental values for the kinetic parameters of phenanthridine oxidation by guinea pig or rabbit liver aldehyde oxidase using common spectrophotometric methods have not been successful due to a lower limit of detection. in the present study, a new spectrofluorimetric assay in combination with a multivariate calibration method for enzymatic kinetic study of aldehyde oxidase ...

microwave assisted fluidized bed drying is a novel drying technique which reduces drying time and yields higher quality products. in this study the effect of this method on color changes of whole and cut hazelnut kernels was investigated. the parameters of color and resulting total color change, chroma, hue angle and browning index were also calculated during drying in three temperatures (40, 5...