Unlike systems of batch analysis, continuous flow systems possesskinetic parameters. Associated with the steady state are such measurements as noise level and drift. This study reports on kinetic parameters associated with the transient state between the steady states including time required to change from base-line steady state to sample steady state and vice versa, characteristics of this cha...

We are interested in finding the kinetic parameters of a chemical reaction. Previous methods for finding these parameters rely on the dynamic behaviour of the system. This means that the methods are time-sensitive and often rely on non-linear curve fitting. In the same manner as previous techniques, we consider the concentrations of chemicals in a reaction. However, we investigate the static be...

An efficient design of in situ combustion depends on accurate kinetic modeling of the crude oil oxidation. The kinetic triplet of the oxidation reactions of a heavy oil sample was investigated. Once the kinetic triplet is known, the kinetic equation would be deconvolved. The crude oil sample was obtained from Kuh-E-Mond reservoir, located in the southwest of Iran. The samples were analyzed usin...

A Multi-objective optimization procedure has been developed to determine some kinetic parameters of free radical polymerization of vinyl acetate based on genetic algorithm. For this purpose, mathematical modeling of free radical polymerization of vinyl acetate is carried out first and then selected kinetic parameters are optimized by minimizing objective functions defined from comparing exp...

the aim of this study was to determine time dependent effects of high intensity interval training (hiit) on oxygen kinetics in young males. 40 active students were randomly assigned to four groups: one session of hiit, two sessions of hiit, four sessions of hiit and control. both hiit and control groups performed the incremental test on an ergometer bicycle. two days after the pretest, training...

the present work is focused on the degradation of 4-chloro-2-nitrophenol in aqueous solution containing nano titanium dioxide, hydrogen peroxide and the combination of nano-tio2/h2o2. the effect of experimental parameters, such as the amount of nano- tio2 concentration of h2o2, initial concentration of 4-chloro-2-nitrophenol and ph on the reaction was investigated. experimental data obtained un...

This study is focused on the development of a systematic computational approach which implements Genetic Algorithm (GA) to find the optimal rigorous kinetic models.A general Kinetic model for hydrogenolysis of dibenzothiophene (DBT) based on Langmuir-Hinshelwood type has been obtained from open literature. This model consists of eight continuous parameters(e.g., Arrhenus  and Van't...

a semi-batch crystallization system is used to determine growth kinetics and morphology of barium carbonate crystals, under a constant ph value and constant temperature in the various relative supersaturations. results show that crystal growth rate satisfies a first-order kinetic expression at high relative supersaturation, while at relative supersaturation values lower than 3,  the kinetic exp...

It is often necessary to analyze the time response of a tracer. A common way of analyzing the tracer time response is to use a compartment model and estimate the model parameters. The model parameters are generally physiologically meaningful and called “kinetic parameters”. In this paper, we simultaneously estimate both the kinetic parameters at each voxel and the model-based plasma input funct...

kinetic monte carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. la-containing perovskites including lafeo3, lanio3, lacoo3 and lamno3 was studied as catalyst for oxalic acid ozonation. the reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. the rate constants val...