In the present study, we report the delivery of anti-cancer drug curcumin to cancer cells using mesoporous silica materials. A series of mesoporous silica material based drug delivery systems (S2, S4 and S6) were first designed and developed through the amine functionalization of KIT-6, MSU-2 and MCM-41 followed by the loading of curcumin. The curcumin loaded materials were characterized with s...

Silica mesoporous nanocomposite films containing graphene nanosheets and gold nanoparticles have been prepared via a one-pot synthesis using silicon tetrachloride, gold(III) chloride tetrahydrate, a 1-N-vinyl-2-pyrrolidone dispersion of exfoliated graphene and Pluronic F127 as a structuring agent. The composite films have shown graphene-mediated surface-enhanced Raman scattering (G-SERS). Graph...

New photocatalysts were obtained by immobilization of titanium and gold species on zeolite Y, hierarchical MCM-48 KIT-6 supports with microporous, mesoporous cubic structure. The samples characterized X-ray diffraction (XRD), N2-physisorption, scanning transmission electron microscopy (SEM/TEM), diffuse reflectance UV–Vis spectroscopy (DRUV-Vis), photoelectron (XPS), Raman photoluminescence spe...

The activity of Ni supported on mesoporous SBA-15, MCM-41, KIT-6, and a sol-gel prepared Ni/γAl2O3, for catalysing methane dry reforming was investigated. The chemical and physical characteristics of the catalysts before and after catalytic testing were investigated using X-Ray diffraction, X-ray Photoemission Spectroscopy, Transmission Electron Microscopy, Scanning Electron Microscopy / Energy...

Mesoporous silica nanoparticles with properly designed textural properties and tailored release of corrosion inhibitors are highly efficient smart carriers for advanced anticorrosive nanocomposite coatings.

objective(s): this paper describes coating of magnetite nanoparticles (mnps) with amorphous silica shells.   materials and methods: first, magnetite (fe3o4) nps were synthesized by co-precipitation method and then treated with stabilizer molecule of trisodium citrate to enhance their dispersibility. afterwards, coating with silica was carried out via a sol-gel approach in which the electrostati...

Tetraethylaluminates of the divalent lanthanides ytterbium and samarium were grafted onto large-pore cubic periodic mesoporous silica (PMS) KIT-6, which had been dehydroxylated at 500 degrees C (specific surface area a(s): 500 m(2)g(-1); mesopore volume V(p): 1.06 cm(3)g(-1); main pore diameter: 85 A). The bimetallic materials [Ln(AlEt(4))(2)]@KIT-6(-500) were analysed by DRIFT spectroscopy, el...