The aging of a nanocrystalline equiatomic ZnSe alloy produced by mechanical alloying was investigated using X-ray diffraction (XRD) and differential scanning calorimetry (DSC) techniques. The measured XRD patterns showed that Se atoms located at interfacial component migrated with aging giving raise to a crystalline selenium (c-Se) phase. DSC spectra of heat-treated samples at temperatures abov...

Abstroct Fine cobalt and silver powders have been ball-milled to yield a granular solid of composition CoSoAg7a in the form of coarse powder. The material is an intimate mixture of grains of fcc CO in a silver matrix. The cobalt is in the single-domain size range, and the samples exhibit coercivity (0.07 T at 296 K) and unusual thermomagnetic effects , including field-induced unidirectional ani...

Powderous crystalline materials of the composition Fe3−xMnxC have been prepared by first synthesizing Fe3C via mechanical alloying in a planetary mill followed by the addition of elemental manganese and arc-plasma melting or via the classic ceramic route in an electric furnace. The milling time for the synthesis of Fe3C was significantly reduced through adjusting the parameters of the planetary...

A novel approach for depositing hydroxyapatite (HA) films on titanium substrates by using mechanical alloying (MA) technique has been developed. However, it was shown that one-hour heat treatment at 800°C of such mechanically coated HA layer leads to partial transformation of desired HA phase to beta-tri-calcium phosphate (β-TCP) phase. It appears that the grain boundary and interface defects f...

X-ray absorption fine structure(XAFS) is used to investigate the local structural change of Fe60Cu40 and FegoCu20 with the ball milling time. The XAFS results verify that the solid solution of mechanically alloyed Fe-Cu samples are inhomogeneous. We propose that the bcc to fcc structural transformation of Fe small particles of Fe60Cuq0(160h) is induced by interfacial Cu atoms dissolving in smal...

Zinc based alloys have recently attracted great attention as promising biodegradable metals. Zinc exhibits moderate degradation rates in biological fluid and the zinc releases during the degradation process is considered safe to human systems. However, these materials exhibit critical limitations in terms of mechanical properties for medical applications. Adding alloying elements as well as gra...

Cobalt sulfide (Co9S8) particles are compounded as the electrode materials of supercapacitors by a mechanical alloying method. They show excellent properties including good cycling stability and high specific capacitance. A supercapacitor is assembled using Co9S8 as the anode and activated carbon (AC) as the cathode. It gains a maximum specific capacitance of 55 F ̈g ́1 at a current density of 0....

Andrew F. May,1 Jean-Pierre Fleurial,2 and G. Jeffrey Snyder3 1Department of Chemical Engineering, California Institute of Technology, 1200 East California Boulevard, Pasadena, California 91125, USA 2Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, California 91109, USA 3Department of Materials Science, California Institute of Technology, 1200 East ...