نتایج جستجو برای: mechanism
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reaction mechanism among indoline-2,3-dione, pyrrolidine-2-carboxylic acid and (z)-2-(1-(2-hydroxynaphthalen-1-yl)ethylidene)hydroxycarboxamide to form 1’-((((aminooxy)carbonyl)amino)methyl)-2’-(1-hydroxynaphthalen-2-yl)-2’-methyl-1’,2’,5’,6’,7’,7a’-hexahydrospiro[indoline-3,3’-pyrrolo[1,2-a]imidazole-2-one was investigated using density functional theory (dft) at b3lyp basis theory. the three-...
in this paper, the effects of roll center height of mcpherson suspension mechanism on dynamic behaviour of a vehicle is studied first and then the optimum location of roll center of this suspension system is determined for a conceptual class a vehicle. adams/car software was used for analysis of vehicle dynamic behaviour in different positions of suspension roll center, then optimization proces...
ball mills are common grinding equipment in mineral processing industries. ball wear results from three mechanisms namely impact, abrasion and corrosion. of these, the corrosion mechanism is the least investigated, due to its chemical-electrochemical nature. therefore, the aims of this research were to investigate the grinding chemistry influence (slurry ph, solid percentage, water chemistry an...
uv/tio2 photocatalysis of chelated copper in aqueous solutions has been performed starting from cu(ii)-tartaric acid, cu(ii)-citric acid, cu(ii)-edta and cu(ii)-dtpa,in the presence of oxygen and at acidic ph. the photocatalytic reaction obeys first-order kinetic equation. the influence of cu(ii) on photocatalytic oxidation of organic ligands and how the various organics will affect the treatmen...
the output error of the globoidal cam mechanism can be considered as a relevant indicator ofmechanism performance, because it determines kinematic and dynamical behavior of mechanicaltransmission. based on the differential geometry and the rigid body transformations, themathematical model of surface geometry of the globoidal cam is established. then we present theanalytical expression of the ou...
the stacking mechanism of the 1h-4h proton transfer in 4-pyridone, 4-pyridinthione and p-aminopyridineare constructed. for quantitative description of this process by means of the quamtumchemicalmethod density functional theory (dft) the activation energy (
The present paper compares full kinetics mechanisms in numerical modelling of porous radiant burners (PRB), with their reduced forms. The two most frequently used mechanisms of methane combustion (GRI3.0 and Miller) were selected and their effects were examined on temperature, species concentration, burning speed, and pollutant emission. While the findings of numerical simulation of PRB sho...
previous, intravenous immunoglobulin (ivig) has been used for treatment of patients with immunodeficiency. however, recent studies have shown that ivig is a suitable approach for treatment of inflammatory and autoimmune diseases. although the exact mechanism of ivig action is not well known, recent findings have demonstrated that ivig impacts on expression and function of fc receptors of immuno...
the kinetics and mechanism of the reaction between benzaldehyde 1, malononitrile 2 and dimedone 3 in a mixture of ethanol and water as solvents in the presence of fructose as a biodegradable catalyst has been studied by the spectroscopic method (uv-vis spectrophotometry method). the influence of various parameters (temperature, solvent and concentration) was studied on the reaction by means of ...
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