The optical and structural properties of sol–gel prepared polycrystalline films of Cerium doped Lutetium and Yttrium oxyorthosilicates (Ce:LYSO) are investigated by means of optical spectroscopy, XRD diffraction and Raman spectroscopy. The sol–gel samples are compared to commercially available Ce-doped LYSO single crystals, and a detailed study of the emission properties from the different ceri...

PURPOSE The aim of the present study was to synthetize and characterize novel sol-gel organic-inorganic hybrid materials to be used for controlled drug delivery application. MATERIALS AND METHODS Organic-inorganic hybrid class I materials based on poly(epsilon-caprolactone) (PCL 6, 12, 24 and 50 wt%) and zirconia-yttria (ZrO2-5%Y2O3) were synthesized by a sol-gel method, from a multicomponent...

Previous studies have shown that the barrier effect and the performance of organic-inorganic hybrid (OIH) sol-gel coatings are highly dependent on the coating deposition method as well as on the processing conditions. However, studies on how the coating deposition method influences the barrier properties in alkaline environments are scarce. The aim of this experimental research was to study the...

Sol–gel chemistry is an efficient tool to control the morphology and reactivity of solids. Drying is the crucial step due to the capillary forces exerted during the classic ambient drying process, which induces the collapse of the wet gel porosity. The use of N, N-dimethylformamide (DMF), a newly found DCCA were found to be effective in the sol–gel synthesis of crack-free silica gel monolith fr...

An optical urea biosensor was fabricated by stacking several layers of sol-gelfilms. The stacking of the sol-gel films allowed the immobilization of a Nile Bluechromoionophore (ETH 5294) and urease enzyme separately without the need of anychemical attachment procedure. The absorbance response of the biosensor was monitoredat 550 nm, i.e. the deprotonation of the chromoionophore. This multi-laye...

We report that oxidized multiwalled carbon nanotubes (MWCNTs) can be synchronously dispersed and functionalized in TiO2 sol via an in situ sol-gel process. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and atomic force microscopy (AFM) were used to characterize the functionalized MWCNTs. The results revealed that the hydrolysis and condensat...