In the centrosymmetric mononuclear title complex, [Cu(C₁₈H₂₀N₂O₂)₂], the Cu(II) atom is four-coordinated in a trans-CuN₂O₂ square-planar geometry with the N-Cu-O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl-benzene and 2,4-dimethyl-benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69...

The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth-oxy-2-[(4-methyl-phen-yl)imino-meth-yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu-O(deprotonated phenolate) bond and a weak Eu-O(...

Mononuclear and icosanuclear spin-crossover complexes, [Fe] [Fe 20 ], were synthesized. has a bis-chelate structure, while ] ring-shape structure comprising four [2 × 2] grid moieties mononuclear units.

Tailoring materials to obtain unique, or significantly enhanced material properties through rationally designed structures rather than chemical constituents is principle of metamaterial concept, which leads to the realization of remarkable optical and mechanical properties. Inspired by the recent progress in electromagnetic and mechanical metamaterials, here we introduce the concept of ferroele...

As socie ty becomes more comfortable discussing genetics and its related ethics, a new technology is blossoming in the background. Nanotechnology may speak the same societal language as does genetics, in that both technological movements involve tiny science and large imagination. In a way, it is natural—and almost inevitable—that the genetic revolution and the nanotechnology revolution be comp...

In this work, we present new results about the non-enzymatic detection of lindane by using CuO-MnO2 hierarchical nano-microstructures. The linear range for the determination of lindane is up to 700 μM with a limit of detection of 4.8 nM, which is much lower than for other non-enzymatic lindane sensors.

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Plasmonic nanostructures with a negative Poisson ratio are demonstrated, having the unusual mechanical property of auxetics to expand laterally when being stretched. Using nanomembrane technology, auxetics are shrunk by orders of magnitude, giving simultaneous access to optical properties of plasmonic metamaterials, as well as auxetic mechanical properties on the nanoscale.