sr5nb4o15 – nb2o5 nanocomposites were synthesized in 2 and 4 m koh aqueous solutions, via a non-stoichiometric 1:2 sr:nb molar ratio hydrothermal method at 160°c for 48 h (s1 and s2, respectively). sr(no3)2 and nb2o5 were used as raw materials. the synthesized nanomaterials were characterized by powder x-ray diffraction (pxrd) technique. it was found that sr5nb4o15 has been crystallized in hexa...

We report on the laser damage resistance of ion beam-sputtered oxide materials (Al2O3, Nb2O5, HfO2, SiO2, Ta2O5, ZrO2) and mixtures of Al2O3-SiO2, Nb2O5-SiO2, HfO2-SiO2, Ta2O5-SiO2, and ZrO2-SiO2, irradiated by single 500 fs pulses at 1030 nm. Laser-induced damage threshold (LIDT), refractive index, and bandgaps of the single-layer coatings are measured. For pure oxide materials a linear evolut...

Sr6Nb10O30–Nb2O5 nanocomposite was synthesized in 2M NaOH aqueous solution. A stoichiometric 1:1 Sr:Nb molar ratio hydrothermal method at 120°C was used to synthesize this nanocomposite. Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized nanomaterials were characterized by powder X-ray diffraction (PXRD) technique. It was found that Sr6Nb10O30 was crystallized in tetragonal crystal ...

We combine nanolaminate bilayer insulator tunnel barriers (Al2O3/HfO2, HfO2/Al2O3, Al2O3/ZrO2) deposited via atomic layer deposition (ALD) with asymmetric work function metal electrodes to produce MIIM diodes with enhanced I-V asymmetry and non-linearity. We show that the improvements in MIIM devices are due to step tunneling rather than resonant tunneling. We also investigate conduction proces...

We demonstrate the fabrication by anodization of niobium oxide microcones, several microns long, from aqueous solutions of 1 wt% hydrogen fluoride (HF) with varied sodium fluoride (NaF) concentration (0–1 M). Raman spectroscopy and x-ray diffractometer analysis revealed the as-grown microcones to be crystalline Nb2O5−x with preferred (1 0 0) and (0 1 0) orientations. The overall Nb2O5−x formati...

Er(3+) doped Y2O3 and Nb2O5 modified germanate glasses with different Er(3+) concentrations were prepared. J-O intensity parameters were computed to estimate the structural changes due to the additions of Y2O3 and Nb2O5. The main mid-infrared spectroscopic features were investigated. To shed light on the observed mid-infrared radiative behavior, 975 nm and 1.53 μm emission spectra along with th...

An ultra high dielectric constant nanocomposites comprising of poly(vinylidene fluoride) (PVDF) as a polymer matrix and niobium pentoxide (Nb2O5)-reinforced graphene oxide (GO) have been successfully developed using solution casting technique. Scanning electron microscopy (SEM) demonstrates that the homogeneous dispersion Nb2O5 GO within PVDF was realized. The electrical properties resulting PV...

Kinetics of hydrogen absorption and desorption reactions was investigated on the MgH2 composite doped with 1 mol% Nb2O5 as a catalyst by ballmilling. The composite after dehydrogenation at 200 °C absorbed gaseous hydrogen of ~ 4.5 mass% even at room temperature under lower pressure than 1 MPa within 15 sec and finally its capacity reached more than 5 mass%. On the other hand, the catalyzed MgH2...

A number of known catalysts, which have been proven to be very effective for several hydrogen species, were studied in order to determine their effects on the hydrogen ab/desorption properties of KSiH3. Among all the catalysts used in this work, mesoporous Nb2O5 is found to be quite effective, with a reduction in activation energy from 142 kJ mol(-1) for pristine KSi to 63 kJ mol(-1) for mesopo...