The three-coordinate imidos (dtbpe)Ni═NR (dtbpe = (t)Bu2PCH2CH2P(t)Bu2, R = 2,6-(i)Pr2C6H3, 2,4,6-Me3C6H2 (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni-N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate HC≡CPh to form the amide acetylide species (dtbpe)Ni{NH(Ar)}(C≡CPh). In the case of R = 2,6-(i)Pr2C6H3, reductive carbonylation result...

XPS depth profiles were used to investigate the effects of rapid thermal annealing under varying conditions on the structural, magnetic and optical properties of Ni-doped ZnO thin films. Oxidization of metallic Ni from its metallic state to two-valence oxidation state occurred in the film annealed in air at 600 C, while reduction of Ni2þ from its two-valence oxidation state to metallic state oc...

Introduction: Among the magmatic iron meteorites, group IVB irons have some unusual characteristics, such as high bulk Ni (15-18 wt%), high refractory elements (e.g., Ir), low volatile elements (e.g., Ga, Ge) [1, 2], fast cooling rates and a small parent body [3, 4]. IVB irons do not have a Widmanstatten pattern as in lower Ni IIIAB or IVA irons. Instead, IVB irons have a plessite structure wit...

Cowpeas grown in nutrient solutions, from which Ni had been removed by a ligand exchange technique, accumulated urea in most tissues. Urea levels were highest (up to 3.1 percent dry weight) in necrotic leaf tips. Urea accumulation in Ni-deficient cowpea tissues amounted to about 1 percent of the total N. The accumulation of urea was presumably associated with the catabolism of N compounds in ol...

Density functional theory calculations were used to investigate the stability of single walled carbon nanotubes (CNTs) attached to nanoparticles. The total energies and the adhesion energies between the CNTs and the nanoparticles were calculated for systems where the nanoparticles were either pure Ni or Ni carbide. It was found that the adhesion between the CNT and a pure Ni cluster is stronger...

Hyperaccumulation of Ni by plants is hypothesized to function as an elemental defense against herbivores and pathogens. Laboratory experiments have documented toxic effects to herbivores consuming high-Ni plant tissues, but this paper reports the first experiment to examine the defensive effectiveness of Ni hyperaccumulation under field conditions. The experiment was conducted at an ultramafic ...

We report the synthesis and characterization of new Ni(x)Ru(1-x) (x = 0.56-0.74) alloy nanoparticles (NPs) and their catalytic activity for hydrogen release in the ammonia borane hydrolysis process. The alloy NPs were obtained by wet-chemistry method using a rapid lithium triethylborohydride reduction of Ni(2+) and Ru(3+) precursors in oleylamine. The nature of each alloy sample was fully chara...

Clethra barbinervis Sieb. et Zucc. accumulates Nickel (Ni) and Cobalt (Co) at high concentrations., We hypothesized that C. barbinervis cannot distinguish between Ni and Co because of the similar chemical properties of these two elements. To confirm this hypothesis and understand the role of these elements in C. barbinervis, we conducted a hydroponic split-root experiment using Ni and Co soluti...

The aim of this study was (i) to investigate alternatives to the very toxic Ni(C0)4, (ii) optimization of the parameters for Ni film growth, and (iii) characterization of the film morphology. The thermal behaviour of the precursors bis(dirnethylglyoximato)Ni(II), [Ni(dmg)2], bis(2,2,6,6-tetramethyl-3,5-heptandionato)Ni(II), [Ni(thd)2], N,N'-ethylenebis(2,4-pentandioniminoato)Ni(II), [Ni(enacac)...

Various morphologies of multi-walled carbon nanotubes (MWNTs) are grown catalytically on metalalloy probes in counterflow diffusion flames using methane as fuel. Carbon nanotube (CNT) properties and morphologies are investigated as functions of local gas-phase temperatures, C-related species concentrations (e.g. C2H2, CO), sampling positions, C2H2 adding to the fuel, and metal-alloy composition...