the reaction between ni(ii), co(ii), cr(iii) bitrates, ni(ii) chloride and ambidentate a-keto ylide benzoylmethylenetriphenylphosphine (bppy) resulted in isolation of [ni(bppy)2](no3)2.2h2o, [ni(bppy)2]cl2, [co(bppy)2](no3)2 and [cr(bppy)3](no3)3; 2h2o. the compounds were characterized by elemental analyses and infrared 1hnmr spectroscopy, molar conductivity in solution and molecular weight mea...

the performance of olive stone activated carbon (osac) for sorption of cu2+, zn2+ and ni2+ ions was investigated via batch technique. osac materials were prepared under different physially activation conditions. olive stone waste was physically activated with n2 gas and steam gas at 900oc at 3.5h hold time (osac-3) was choice as the best one for cu2+, zn2+ and ni2+ removal. characterization for...

4(4-nitrophenyl-zao)-2-(2-methoxy phenimino)-phenol and its coordination compounds with ni(ii), cu(ii), co(ii) and fe(iii) have been synthesized and characterized by elemental analyses, ft-ir, far-ir, near ir, uv-vis, mass spectrometry and molar conductivity and their electrochemical behaviours are reported.

the modified surface of typha latifolia l. root (mstl), as an alternative economical adsorbent, wasused for the removal of ni (ii) and cd(ii) ions from aqueous solutions. the effect of initial ph, initialconcentration of metal ion, and contact time was investigated in a batch system at room temperature.the kinetics data could be fitted well by pseudo-second-order model with correlation coeffici...

in the current investigation a novel nano hybrid adsorbent mcm-41/n-(3-trimethoxysilyl)-propyl)diethylenetriamine (mcm-41/tmspdeta) was prepared and was characterized using dls (dynamic light scattering), fourier transform infrared (ftir), x-ray diffraction (xrd), brunauer–emmett–teller (bet) analytical techniques and transmission electron microscopy (tem). the synthesized mcm-41/tmspdeta adsor...

this paper discusses the biosorption of ni(ii) ions from aqueous solutions by bacillus sphaericus biomass. the biosorption process was affected by the solution ph, biomass concentration, contact time, temperature and initial ni(ii) concentration respectively. the sorption kinetics and equilibrium data were described well with the pseudo-second order kinetic model and the freundlich isotherm mod...

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n'1,n'2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best performance was...

a pvc membrane ni(ii) ion selective electrode has been constructed using (1e,2e)-bis(2-aminophenyl)n'1,n'2-dihydroxyethanebis as membrane carrier. the electrode exhibited a goodpotentiometric response for ni(ii) over a wide concentration range 1.0×10-4 to 1.0×10-1m with aslope of 29.4±0.5 mv/decade a and a working ph range of 6.5-9.0. it had a fast response time of≤20s. the best perfo...

Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong p...