unsubstituted phthalocyanines of co, fe and mn supported on zinc oxide nanoparticles were prepared and were well characterized with x-ray diffraction (xrd) and scanning electron microscopy (sem). the oxidation of alcohols with tert-butylhydroperoxide (tbhp), in the presence of metallophthalocyanines (mpc) supported on zinc oxide nanoparticles was investigated. these mpc/zno nanocomposites were ...

the reaction of ch₃nh₂ with o₂ on the singlet potential energy surfaces (pes) was carried out using the b3lyp, ccsd(t) and g3b3 theoretical approaches along with 6-311++g(3df,3pd) basis set. the suggested mechanism for the title reaction consists of one pre-reactive complex. from the pre-reactive complex, nine types of products, ch2nh+h2o2, ch3nh+ooh, nh2cho+h2o, ch2nho+h2o, nh3+hcooh, ch2nh+h2...

Oxidation of different types of 1,4-dihydropyridines with diphenylpicrylhydrazyl (DPP) and benzoyl peroxide (Bz2O2) as free radical oxidizing agents to pyridine derivatives is reported and a mechanism for this oxidation is also proposed.

the oxidation of ferrous iron (fe2+) in solution using acidithiobacillus ferrooxidans has industrial applications exclusively in the regeneration of ferric iron (fe3+) as an oxidizing agent for the removal of hydrogen sulfide from waste gases, desulfurization of coal, leaching of non-ferrous metallic sulfides and treatment of acid mine drainage. the aim of this investigation was to increase the...

in order to enhance the performance of interconnects which are used in solid oxide fuel cells (sofcs), a protective/conductive coating can be applied. in this research aisi 430 ferritic stainless steel was coated in a mn-base pack mixture by pack cementation method. in order to evaluate the oxidation behavior, isothermal oxidation was accomplished for 200 h at 800 ºc. electrical behavior was al...

Macrocycles and p-benzoquinones (p-BQ) have been generally connected as potential co-synergist redox models in aerobic oxidation. To get insight for the synergist oxidation of hydroquinones (H2Q), thus, we synthesized and characterized dibenzotetraaza [14]annulene type macrocycles of FeIII and CoII metal ions and described by utilizing different examinations inc...