It is generally acknowledged that Pb(2+), which is sequestered by live cells from their direct environment, affects a large number of cellular processes at picomolar to micromolar concentrations. However, resolving the specific molecular targets and mechanisms responsible for the neurotoxic effects of this xenobiotic metal is hampered by the lack of suitable tools to investigate the intracellul...

The fabrication and evaluation of a glassy carbon electrode (GCE) modified with self-doped polyaniline nanofibers (SPAN)/mesoporous carbon nitride (MCN) and bismuth for simultaneous determination of trace Cd2+ and Pb2+ by square wave anodic stripping voltammetry (SWASV) are presented here. The morphology properties of SPAN and MCN were characterized by transmission electron microscopy (TEM), an...

The goal of this work was to synthesize substituted polystyrene for metal extraction and/or depollution by introduction of substituted piperazines as chelatants starting from Merrifield polymer. After transformation of Merrifield’s resin in azidomethyl polystyrene, click-chemistry using copper (I)-catalyzed Huisgen’s reaction (CuAAC) was performed to prepare different polymers grafted with 1,4-...

abstractin this work, the micro powder was the product of cedar leaf (mpcl) is used as a low-cost adsorbent for the removal of pb2+ ions from aqueous solutions. bath experiments were used to determine the best adsorption conditions the adsorption percentage of pb2+ ions mpcl samples at different initial ph, contact time (tc), adsorbent dosage and temperature (t) were investigated. effective rem...

in this work, a novel method is described for the preconcentration of pb2+, cd2+ and zn2+ ions in environmental samples using uniform silanized mesopor (lus-1) functionalized by ethylenediamine groups as a new extractant. the determination of ions is done by inductively coupled plasma optical emission spectrometry (icp-oes). the extraction time and efficiency, ph and amount of adsorbent, minimu...

Avian influenza viruses are capable of crossing the species barrier and infecting humans. Although evidence of human-to-human transmission of avian influenza viruses to date is limited, evolution of variants toward more-efficient human-to-human transmission could result in a new influenza virus pandemic. In both the avian influenza A(H5N1) and the recently emerging avian influenza A(H7N9) virus...

Inorganic lead has been measured in high concentrations in certain streams in Brazil. This study has evaluated the osmoregulatory effects of lead on the native freshwater red crab Dilocarcinus pagei. In order to probe its osmoregulatory and tissue volume regulatory capabilities and how it would be affected by lead, the crab has been submitted to individual and combined salt and chemical stresse...

A collection of influenza virus PB2 mutant genes was prepared, including N-terminal deletions, C-terminal deletions, and single-amino-acid insertions. These mutant genes, driven by a T7 promoter, were expressed by transfection into COS-1 cells infected with a vaccinia virus encoding T7 RNA polymerase. Mutant proteins accumulated to levels similar to that of wild-type PB2. Immunofluorescence ana...

Classical xerogels are robust, inexpensive and nontoxic materials with low-ordered nanoporous structures. In water streams where the pH is higher than the Point of Zero Charge, the surface of classical xerogels such as tetraethoxy orthosilan (TEOS) xerogel is negatively charged. It was assumed that a xerogel can work as a strong adsorbent for metal ions without further modification. Therefore, ...

The crystal structure of Pb4O(VO4)2 has been solved using crystals prepared by high-temperature solid-state reactions. The compound is orthorhombic, Pnma, a 22.7276(9), b 11.5346(4), c 7.4349(3) Å, V 1949.09(13) Å3, Z = 8. The structure was solved by direct methods and refined on the basis of F2 of all unique reflections to R1 = 0.029 (wR2 = 0.052), calculated for 3052 unique observed reflectio...