This study examined the ability of a photocatalyst mixed in a denture base resin to decompose organic substances which adhered to the denture base resin surface. The photocatalyst was mixed with denture base resin at concentrations of 0, 5, 10, and 15% (w/w). Decomposition test, bending test, and surface roughness measurement were performed at 1, 7, 30, 90, and 180 days after polymerization. De...

To reduce a film-diffusional resistance in the very vicinity of the photocatalyst surface, titanium oxide particles containing a small amount of adsorbent particles (310 %) are immobilized on a stainless steel screen by a spraying method and its performance is investigated by decomposing 2,4-dinitrophenol in water. It is found that the activity of this photocatalyst screen is higher than that o...

A dressed-phonon-phonon (DPP) assisted photocatalyst reaction was carried out to increase the visible light responsibility, where the photon energy of the radiation, which ranged from visible to infrared light is less than band gap energy of the photocatalyst (ZnO, 3.3 eV). The dependence of the photocurrent on excitation power indicated that two-step excitation occurred in DPP-assisted process...

The photocatalytic oxidation of gaseous chlorobenzene (CB) by the 365nm-induced photocatalyst La/N-TiO2, synthesized via a sol-gel and hydrothermal method, was evaluated. Response surface methodology (RSM) was used to model and optimize the conditions for synthesis of the photocatalyst. The optimal photocatalyst was 1.2La/0.5N-TiO2 (0.5) and the effects of La/N on crystalline structure, particl...

The aluminum-based metal-organic framework (MOF) made from 2-aminoterephthalate is a photocatalyst for oxygen evolution. This MOF can be modified by incorporating Ni2+ cations into the pores through coordination to the amino groups, and the resulting MOF is an efficient photocatalyst for overall water splitting.

The photoredox-mediated coupling of benzylic ethers with Schiff bases has been accomplished. Direct benzylic C-H activation by a combination of a thiol catalyst with an iridium photocatalyst and subsequent radical-radical coupling with secondary aldimines affords a variety of β-amino ether products in good to excellent yields. Mechanistic studies suggest that a reductive quenching pathway of th...

A hollow Fe2O3-TiO2-PtOx photocatalyst for visible light H2 generation was prepared from nanosized MIL-88B consisting of coordinatively unsaturated metal centers as a hard template. This photocatalyst is composed of hybrid metal oxide-TiO2 with controllable wall thickness and two different cocatalysts that are separately located on two surface sides.

A new strategy is described to immobilize photoactive C(60) aminofullerene on silica gel (3-(2-succinic anhydride)propyl functionalized silica), thus enabling facile separation of the photocatalyst for recycling and repeated use. An organic linker moiety containing an amide group was used to anchor C(60) aminofullerene to the functionalized silica support. The linker moiety prevents aqueous C(6...

A novel Ag-based photocatalyst Ag2Nb4O11 has been obtained, which exhibits universal high-efficiency photodegradation activity for rhodamine B (RhB), methylene blue (MB) and methyl orange (MO) organic dyes. The cycling ability (40 times) and recovery characteristics indicate that the Ag2Nb4O11 photocatalyst has high stability, durability and regeneration ability.

a floating polymer-supported photocatalyst based on polystyrene impregnated with titaniumdioxide particles was developed using a facile solvent-cast method at ambient temperature. the preparedphotocatalysts were characterized by x-ray diffraction, scanning electron microscopy and fourier transforminfrared spectroscopy. the photocatalytic activity of the developed photocatalysts was investigated...