Two intramolecularly donor-stabilized silenes, l-(8-dimethylamino-l-naphthyl)-l,2,2-tris(trimethylsilyl)silene (1 ), and l-[bis-2 ,6 -(dimethylaminomethyl)phenyl]-l,2 ,2 -tris(trimethylsilyl)silene 2, were studied by 2 9 Si and C NMR spectroscopy, using polarization transfer techniques in order to determine coupling constants V (2 9 Si,2 9 Si) in = 1,2, 3) and '/ ( 2 9 Si,l3 C) together with is...

To search the infrared behaviour of the propagator in three dimensional QED ordinary perturbative method is not appropriate because of its bad infrared divergences[4].Assuming spectral representation and LSZ reduction formula,we evaluate the infrared behaviour or the mass singularity of the fermion propagator in three dimensional QED as in four dimension.In quenched case with bare photon mass w...

To search the infrared behaviour of the propagator in three dimensional QED ordinary perturbative method is not appropreate because of its bad infrared divergences[4].Assuming spectral representation and LSZ reduction formula,we evaluate the infrared behaviour or the mass singularity of the fermion propagator in three dimensional QED as in four dimension.In quenched case with bare photon mass w...

We examine the photo-assisted polarization loop in a BiFeO3 thin film under UV light illumination. BiFeO3 thin film prepared by pulsed laser deposition method onto the BaTiO3 thin film and the polarization behavior has been measured under poling voltage. Our results show the engineered polarization due to controllable schottky barrier under inverse poling voltage. This control on schottky barri...

a spectrophotometric method is used to determine the acidity constants of some derivatives of 9,10-anthraquinone in binary methanol-water mixtures at 25 °c. there is a linear inverse relationship between pka of all acids and the mole fraction of methanol in the mixed solvent. the influence of substituents in the molecular structure on the ionization constants is discussed.

We have carried out a theoretical study of a series of para-substituted phenoxy radicals in an effort to understand the factors influencing spin and charge density distribution in open-shell systems. The calculations reveal that the distribution of spin and charge are not correlated: cases were found for which spin and charge move together, whereas for other substituents the two quantities exhi...

The indirect scalar NMR spin-spin coupling constants across the H-bonds of the protein ubiquitin were calculated, including the Fermi contact, the diamagnetic spin-orbit, the paramagnetic spin-orbit, and the spin dipole term, employing coupled perturbed density functional theory in combination with the B3LYP functional and different basis sets: (9s,5p,1d/5s,1p)[6s,4p,1d/3s,1p] and (11s,7p,2d/5s...

The present study deals with the plane waves moving in a solid medium qualifying for anisotropic, homogeneous, microstretch and elastic properties. Primarily, Christoffel equations have been derived propagation of (coupled longitudinal coupled transverse) medium. A system homogeneous has established to polarization particles wave motion, microrotation Condition solvability linear applied derive...

In the previous chapter, we discussed devices based on deliberately introduced birefringence in an optical fiber, thus utilizing the polarization effects to our advantage. In Chapter 10, we discuss the detrimental aspect of birefringence in optical fibers—namely, polarization mode dispersion (PMD). The existence of birefringence in a fiber implies that the fiber supports two orthogonally polari...